Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds
Электронный архив УГЛТУ
Информация об архиве | Просмотр оригиналаПоле | Значение | |
Заглавие |
Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds
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Автор |
Pavlova, I. S.
Pervova, I. G. Belov, G. P. Khasbiullin, I. I. Slepukhin, P. A. |
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Тематика |
ETHYLENE
IRON FORMAZANATES OLIGOMERIZATION ORGANOALUMINUM COMPOUNDS CATALYTIC BEHAVIOR ETHYLENE OLIGOMERIZATIONS HEXENE ISOMERS IRON COMPLEX METHYLALUMINOXANE ORGANOALUMINUM COMPOUNDS ALUMINUM COMPOUNDS BYPRODUCTS ETHYLENE ISOMERS MASS SPECTROMETRY OLIGOMERIZATION OLIGOMERS SYNTHESIS (CHEMICAL) IRON COMPOUNDS |
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Описание |
A number of iron(II) complexes have been synthesized on the basis of benzothiazolylformazans, and their structure and composition have been characterized by elemental analysis, mass spectrometry, and X-ray analysis. The catalytic behavior of Fe(II) formazanates in the reaction of ethylene oligomerization in the presence of various organoaluminum compounds has been studied. Methylaluminoxane facilitates the formation of α-olefins (butene-1, hexene-1) and the byproducts hexene isomers; ethylaluminum dichloride (AlC2H5Cl2) increases the selectivity for alkyltoluenes. © 2013 Pleiades Publishing, Ltd.
This work was supported in part by the Russian Academy of Sciences under Presidium program no. 3 “Energy aspects of deep processing of fossil and renewable carbonaceous resources” and the Russian Foundation for Basic Research, project no. 11 03 90724 mob_st. |
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Дата |
2019-09-20T15:19:00Z
2019-09-20T15:19:00Z 2013 |
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Тип |
Article
Journal article (info:eu-repo/semantics/article) Published version (info:eu-repo/semantics/publishedVersion) |
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Идентификатор |
Pavlova, I. S. Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds / I. S. Pavlova, I. G. Pervova, G. P. Belov [et al.] // Petroleum Chemistry. – 2013. – Vol. 53. – Iss. 2. – P. 127-133.
9655-0441 https://elar.usfeu.ru/handle/123456789/8816 |
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Язык |
en
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Права |
Restricted accedd (info:eu-repo/semantics/restrictedAccess)
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Издатель |
Pleiades Publishing
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Источник |
Petroleum Chemistry
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