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Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds

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Заглавие Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds
 
Автор Pavlova, I. S.
Pervova, I. G.
Belov, G. P.
Khasbiullin, I. I.
Slepukhin, P. A.
 
Тематика ETHYLENE
IRON FORMAZANATES
OLIGOMERIZATION
ORGANOALUMINUM COMPOUNDS
CATALYTIC BEHAVIOR
ETHYLENE OLIGOMERIZATIONS
HEXENE ISOMERS
IRON COMPLEX
METHYLALUMINOXANE
ORGANOALUMINUM COMPOUNDS
ALUMINUM COMPOUNDS
BYPRODUCTS
ETHYLENE
ISOMERS
MASS SPECTROMETRY
OLIGOMERIZATION
OLIGOMERS
SYNTHESIS (CHEMICAL)
IRON COMPOUNDS
 
Описание A number of iron(II) complexes have been synthesized on the basis of benzothiazolylformazans, and their structure and composition have been characterized by elemental analysis, mass spectrometry, and X-ray analysis. The catalytic behavior of Fe(II) formazanates in the reaction of ethylene oligomerization in the presence of various organoaluminum compounds has been studied. Methylaluminoxane facilitates the formation of α-olefins (butene-1, hexene-1) and the byproducts hexene isomers; ethylaluminum dichloride (AlC2H5Cl2) increases the selectivity for alkyltoluenes. © 2013 Pleiades Publishing, Ltd.
This work was supported in part by the Russian Academy of Sciences under Presidium program no. 3 “Energy aspects of deep processing of fossil and
renewable carbonaceous resources” and the Russian Foundation for Basic Research, project no. 11 03 90724 mob_st.
 
Дата 2019-09-20T15:19:00Z
2019-09-20T15:19:00Z
2013
 
Тип Article
Journal article (info:eu-repo/semantics/article)
Published version (info:eu-repo/semantics/publishedVersion)
 
Идентификатор Pavlova, I. S. Ethylene oligomerization mediated by iron formazanates and organoaluminum compounds / I. S. Pavlova, I. G. Pervova, G. P. Belov [et al.] // Petroleum Chemistry. – 2013. – Vol. 53. – Iss. 2. – P. 127-133.
9655-0441
https://elar.usfeu.ru/handle/123456789/8816
 
Язык en
 
Права Restricted accedd (info:eu-repo/semantics/restrictedAccess)
 
Издатель Pleiades Publishing
 
Источник Petroleum Chemistry