Synthesis of Cu(II)-containing TiO2-SiO2 binary xerogels by hydrolysis of a mixture of tetrabutoxytitanium, tetraethoxysilane, and copper(II) chloride in a water-ammonia atmosphere
Электронный архив УГЛТУ
Информация об архиве | Просмотр оригинала| Поле | Значение | |
| Заглавие |
Synthesis of Cu(II)-containing TiO2-SiO2 binary xerogels by hydrolysis of a mixture of tetrabutoxytitanium, tetraethoxysilane, and copper(II) chloride in a water-ammonia atmosphere
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| Автор |
Shishmakov, A. B.
Molochnikov, M. S. Antonov, D. O. Koryakova, O. V. Seleznev, A. S. Petrov, L. A. |
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| Описание |
A Cu(II)-containing binary xerogel TiO2-SiO2 was synthesized by joint hydrolysis of tetrabutoxytitanium, teraethoxysilane and copper(II) chloride dissolved in their mixture. The synthesis was performed in a vapor of 10% aqueous ammonia under static conditions. EPR spectroscopy was used to examine the state of Cu(II) in the xerogel matrix. Data on specific features of the behavior of saccharose within xerogel pores under heating were obtained. The catalytic activity of the xerogel was tested by the kinetic method on model reactions of hydrogen peroxide decomposition and oxidative dehydrogenation of trimethylhydroquinone. © 2013 Pleiades Publishing, Ltd.
The study was financially supported by the Ural Branch of the Russian Academy of Sciences (grant no. 12-I-3-2058. |
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| Дата |
2019-09-20T15:19:02Z
2019-09-20T15:19:02Z 2013 |
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| Тип |
Article
Journal article (info:eu-repo/semantics/article) Published version (info:eu-repo/semantics/publishedVersion) |
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| Идентификатор |
Shishmakov, A. B. Synthesis of Cu(II)-containing TiO2-SiO2 binary xerogels by hydrolysis of a mixture of tetrabutoxytitanium, tetraethoxysilane, and copper(II) chloride in a water-ammonia atmosphere / A. B. Shishmakov, M. S. Molochnikov, D. O. Antonov [et al.] // Russian Journal of Applied Chemistry. – 2013. – Vol. 86. – Iss. 3. – P. 297-303.
1070-4272 https://elar.usfeu.ru/handle/123456789/8825 |
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| Язык |
en
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| Права |
Restricted accedd (info:eu-repo/semantics/restrictedAccess)
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| Издатель |
Pleiades Publishing
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| Источник |
Russian Journal of Applied Chemistry
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