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Minerals of Rare Earth Elements in High-Phosphorus Ooidal Ironstones of the Western Siberia and Turgai Depression

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Заглавие Minerals of Rare Earth Elements in High-Phosphorus Ooidal Ironstones of the Western Siberia and Turgai Depression
 
Автор Rudmin, Maksim Andreevich
Reva, Igor Vitaljevich
Sokol, Ellina
Abdullaev, Elshan
Ruban, Aleksey Sergeevich
Kudryavtsev, Andrey
Tolkachev, Oleg Sergeevich
Mazurov, Aleksey Karpovich
 
Тематика rare earth elements
ooidal ironstones
phosphates
mineral association
complex deposit
редкоземельные элементы
фосфаты
 
Описание The aim of this research was to study the rare earth (REE) minerals in ooidal ironstone deposits of the West Siberian basin and the Turgai depression. Authigenic minerals (monazite and cerite) were described, and their main mineral form was identified as light rare earth element phosphate (LREE-phosphate) in this study. LREE-phosphate is included in ferruginous ooids, peloids, and oncoids and forms a consistent mineral association with Fe-hydroxides (goethite and its hydrated amorphous derivatives) and Fe-rich layered silicates (Fe-illite-smectite, chamosite, berthierine). The constancy of the mineral association in two deposits of different ages indicates a general mechanism behind the formation of these minerals. LREE-phosphates (authigenic monazite) are characterized by microscopic sizes (up to 24 ?m), diverse morphology (mainly spherical or xenomorphic), and occupy spaces between the micro-cortex in ferruginous spheroids. This mineral can be found in other deposits of ooidal ironstone. According to its mineralogical and chemical characteristics, LREE-phosphate mainly belongs to the authigenic (nodular or “gray”) monazite. However, the incomplete (not 100%) correspondence of Kikuchi bands with the reference monazite does not allow its reliable identification. Based on its small size, chemical leaching or bacterial interaction is recommended to extract REE from ooidal ironstone while predicting the associated removal of phosphorus from iron ore due to its dominant phosphate mineral form. Ooidal ironstone should be considered a complex deposit and an unconventional natural type of REE ores as an example of the largest Bakchar and Lisakovsk deposits.
 
Дата 2020-01-10T08:52:32Z
2020-01-10T08:52:32Z
2020
 
Тип Article
Published version (info:eu-repo/semantics/publishedVersion)
Journal article (info:eu-repo/semantics/article)
 
Идентификатор Minerals of Rare Earth Elements in High-Phosphorus Ooidal Ironstones of the Western Siberia and Turgai Depression / M. A. Rudmin [et al.] // Minerals. — 2020. — Vol. 10, iss. 1. — [11, 16 p.].
http://earchive.tpu.ru/handle/11683/57271
10.3390/min10010011
 
Язык en
 
Права Open access (info:eu-repo/semantics/openAccess)
 
Формат application/pdf
 
Издатель Томский политехнический университет
 
Источник Minerals