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Comparison of differential and integral methods for coal oxidation kinetic analysis

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Поле Значение
 
Заглавие Comparison of differential and integral methods for coal oxidation kinetic analysis
 
Автор Slusarskiy (Slyusarsky), Konstantin Vitalievich
Gubin, Vladimir Evgenievich
Gvozdyakov, Dmitry Vasilievich
Tolokolnikov, Anton Andreevich
 
Тематика кинетический анализ
дифференциальные методы
интегральные методы
уголь
 
Описание The influence of two different methods of kinetic analysis on obtained values of kinetic constants of coal oxidation process was studied. The oxidation of T-grade bituminous coal of Kuznetskiy deposit and 2B-grade lignite of Borodinskoe deposit was investigated by means of thermogravimetric analysis. All measurements were carried out with heating rates 2,5, 10, 25 and 40 K/min in temperature range 300-1100 K in air medium. The dependences of activation energy and frequency factor on conversion were obtained using two isoconversional methods: differential method of Freidman and integral method of Kissinger-Akahira-Sunose. The average values of activation energy which were obtained by KAS method were higher by 14.5 % for bituminous coal and 23.3 % for lignite in comparison with values obtained by Freidman method. The same relations were observed for frequency factor values.
 
Дата 2020-01-27T11:08:41Z
2020-01-27T11:08:41Z
2018
 
Тип Conference Paper
Published version (info:eu-repo/semantics/publishedVersion)
Conference paper (info:eu-repo/semantics/conferencePaper)
 
Идентификатор Comparison of differential and integral methods for coal oxidation kinetic analysis / K. V. Slusarskiy (Slyusarsky) [et al.] // Journal of Physics: Conference Series. — 2018. — Vol. 1128 : Thermophysics and Physical Hydrodynamics : 3rd All-Russian Scientific Conference with the School for Young Scientists, 10–16 September 2018, Yalta, Crimea : [proceedings]. — [012076, 7 p.].
http://earchive.tpu.ru/handle/11683/57643
10.1088/1742-6596/1128/1/012076
 
Язык en
 
Права Open access (info:eu-repo/semantics/openAccess)
 
Издатель IOP Publishing