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ABO4 type scheelite phases in (Ca/Sr)MoO4 - BiVO4 - Bi2Mo3O12 systems: synthesis, structure and optical properties

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Заглавие ABO4 type scheelite phases in (Ca/Sr)MoO4 - BiVO4 - Bi2Mo3O12 systems: synthesis, structure and optical properties
 
Автор Mikhaylovskaya, Z. A.
Buyanova, E. S.
Petrova, S. A.
Klimova, A. V.
 
Тематика STRONTIUM BISMUTH MOLYBDATE
CALCIUM BISMUTH MOLYBDATE
KUBELKA-MUNK METHOD
ENERGY GAP
 
Описание Received: 25.03.2021. Revised: 12.04.2021. Accepted: 28.04.2021. Available online: 29.04.2021.
The cation deficient complex oxides of (Ca/Sr)MoO4 - BiVO4 - Bi2Mo3O12 triple system are promising photocatalysts and pigments. Compounds with general formula of Ca1−1.5x-yBix+yФxMo1-yVyO4 and Sr1−1.5x-yBix+yФxMo1-yVyO4 were synthesized by convention solid state technique in the range of 550-720 °C. Two wide regions of the solid solutions (ordinary and superstructured scheelite-type phases respectively) were found for each system. The diffuse scatering of homogeneous samples was investigated in the range of 190-1100 nm. Energy gaps calculated with linear approximation of Kubelka-Munk function decreases with bismuth and vanadium content.
The XPRD data were obtained in Ural-M center of Institute for Metallurgy, Ural Br. of RAS This work is supported by grant of RSF, project № 20-73-10048.
 
Дата 2021-08-09T11:55:13Z
2021-08-09T11:55:13Z
2021-07
 
Тип Article
info:eu-repo/semantics/acceptedVersion
Journal article (info:eu-repo/semantics/article)
 
Идентификатор ABO4 type scheelite phases in (Ca/Sr)MoO4 - BiVO4 - Bi2Mo3O12 systems: synthesis, structure and optical properties / Z. A. Mikhaylovskaya, E. S. Buyanova, S. A. Petrova, A. V. Klimova // Chimica Techno Acta. — 2021. — Vol. 8, No. 2. — № 20218204.
2411-1414
http://elar.urfu.ru/handle/10995/100703
https://www.elibrary.ru/item.asp?id=46407566
10.15826/chimtech.2021.8.2.04
 
Язык en
 
Связанные ресурсы info:eu-repo/grantAgreement/RSF//20-73-10048
Chimica Techno Acta. 2021. Vol. 8. № 2
 
Формат application/pdf
 
Издатель Ural Federal University
Уральский федеральный университет