Stable Sulfuric Vapor Transport and Liquid Sulfur Growth on Transition Metal Dichalcogenides
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригинала| Поле | Значение | |
| Заглавие |
Stable Sulfuric Vapor Transport and Liquid Sulfur Growth on Transition Metal Dichalcogenides
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| Автор |
Chareev, D. A.
Khan, M. E. H. Karmakar, D. Nekrasov, A. N. Nickolsky, M. S. Eriksson, O. Delin, A. Vasiliev, A. N. Abdel-Hafiez, M. |
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| Тематика |
ELECTRONIC PROPERTIES
SINGLE CRYSTALS SULFUR DICHALCOGENIDES GLASS AMPOULES HIGH QUALITY LIQUID SULPHURS LOW-DIMENSIONAL MATERIALS MONO-CRYSTALS QUARTZ GLASS SYNTHETIC ROUTES VAPOR TRANSPORT VAPOR-LIQUID TRANSITION METALS |
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| Описание |
Transition metal dichalcogenides (TMDs) are an emergent class of low-dimensional materials with growing applications in the field of nanoelectronics. However, efficient methods for synthesizing large monocrystals of these systems are still lacking. Here, we describe an efficient synthetic route for a large number of TMDs that were obtained in quartz glass ampoules by sulfuric vapor transport and liquid sulfur. Unlike the sublimation technique, the metal enters the gas phase in the form of molecules, hence containing a greater amount of sulfur than the growing crystal. We have investigated the physical properties for a selection of these crystals and compared them to state-of-the-art findings reported in the literature. The acquired electronic properties features demonstrate the overall high quality of single crystals grown in this work as exemplified by CoS2, ReS2, NbS2, and TaS2. This new approach to synthesize high-quality TMD single crystals can alleviate many material quality concerns and is suitable for emerging electronic devices. © 2023 The Authors. Published by American Chemical Society.
European Research Council, ERC: 854843-FASTCORR; Stiftelsen för Strategisk Forskning, SSF; National Science Council, NSC: 2018-05973; Knut och Alice Wallenbergs Stiftelse: 2018.0060; Vetenskapsrådet, VR: 2018-05393, VR 2015-04608, VR 2016-05980, VR 2019-05304; Energimyndigheten; Council on grants of the President of the Russian Federation: NSh-2394.2022.1.5 M.A.-H. acknowledges the financial support from the Swedish Research Council (VR) under project No. 2018-05393. D.A.C. acknowledges the financial support by the Grant of the President of the Russian Federation for the state support of the leading scientific schools of the Russian Federation No. NSh-2394.2022.1.5. O.E. acknowledges the financial support by the Knut and Alice Wallenberg Foundation through Grant No.2018.0060. O.E. also acknowledges the support by the Swedish Research Council (VR), the Foundation for Strategic Research (SSF), the Swedish Energy Agency (Energimyndigheten), the European Research Council (854843-FASTCORR), eSSENCE, and StandUP. The computations/data handling was enabled by resources provided by the Swedish National Infrastructure for Computing (SNIC). Financial support from Vetenskapsrådet (Grant Nos. VR 2015-04608, VR 2016-05980, and VR 2019-05304) and the Knut and Alice Wallenberg Foundation (Grant No. 2018.0060) is acknowledged. Computations were enabled by resources provided by the Swedish National Infrastructure for Computing (SNIC) at PDC and NSC, partially funded by the Swedish Research Council through grant agreement no. 2018-05973. |
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| Дата |
2024-04-05T16:18:28Z
2024-04-05T16:18:28Z 2023 |
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| Тип |
Article
Journal article (info:eu-repo/semantics/article) |info:eu-repo/semantics/publishedVersion |
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| Идентификатор |
Chareev, DA, Khan, MEH, Karmakar, D, Nekrasov, AN, Nickolsky, MS, Eriksson, O, Delin, A, Vasiliev, AN & Abdel-Hafiez, M 2023, 'Stable Sulfuric Vapor Transport and Liquid Sulfur Growth on Transition Metal Dichalcogenides', Crystal Growth and Design, Том. 23, № 4, стр. 2287-2294. https://doi.org/10.1021/acs.cgd.2c01318
Chareev, D. A., Khan, M. E. H., Karmakar, D., Nekrasov, A. N., Nickolsky, M. S., Eriksson, O., Delin, A., Vasiliev, A. N., & Abdel-Hafiez, M. (2023). Stable Sulfuric Vapor Transport and Liquid Sulfur Growth on Transition Metal Dichalcogenides. Crystal Growth and Design, 23(4), 2287-2294. https://doi.org/10.1021/acs.cgd.2c01318 1528-7483 Final All Open Access, Hybrid Gold, Green https://www.scopus.com/inward/record.uri?eid=2-s2.0-85151269182&doi=10.1021%2facs.cgd.2c01318&partnerID=40&md5=33dd73165977a14c8712fa5b3e2dccff https://pubs.acs.org/doi/pdf/10.1021/acs.cgd.2c01318 http://elar.urfu.ru/handle/10995/130317 10.1021/acs.cgd.2c01318 85151269182 000955393900001 |
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| Язык |
en
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| Права |
Open access (info:eu-repo/semantics/openAccess)
cc-by https://creativecommons.org/licenses/by/4.0/ |
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| Формат |
application/pdf
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| Издатель |
American Chemical Society
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| Источник |
Crystal Growth & Design
Crystal Growth and Design |
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