Magnetic Anisotropy of Single-Ion Magnet (PPh4)2 [ReF6]·2H2O
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригинала| Поле | Значение | |
| Заглавие |
Magnetic Anisotropy of Single-Ion Magnet (PPh4)2 [ReF6]·2H2O
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| Автор |
Taran, L. S.
Elfimova, V. Y. Streltsov, S. V. |
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| Описание |
Studying of single-molecule magnets has sprung many surprises such as, e.g., quantum tunneling of the magnetization, which is strongly related to the presence of a magnetic anisotropy. Electron spin resonance and inelastic neutron scattering measurements of (PPh4)2[ReF6]⋅2H2O complex evidence an unprecedented large single-site magnetic anisotropy of D ∼ 35 K in this material. Using state-of-the-art ab initio calculations we found that the single-ion anisotropy is indeed very large (but does not exceed 12 K) and revealed the physical mechanism lying behind this phenomenon. © 2023, The Author(s).
Ural Branch, Russian Academy of Sciences, UB RAS We are grateful to Prof. A. Rogalev for drawing our attention to this Re SIM and E. Komleva for a detailed discussion of the paper. Computations were performed on the Uran supercomputer at the Mikheev Institute of Metal Physics, Ural Branch, Russian Academy of Sciences. |
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| Дата |
2024-04-05T16:19:41Z
2024-04-05T16:19:41Z 2023 |
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| Тип |
Article
Journal article (info:eu-repo/semantics/article) |info:eu-repo/semantics/publishedVersion |
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| Идентификатор |
Taran, LS, Elfimova, VY & Streltsov, SV 2023, 'Magnetic Anisotropy of Single-Ion Magnet (PPh4)2 [ReF6]·2H2O', JETP Letters, Том. 117, № 8, стр. 606-611. https://doi.org/10.1134/S0021364023600623
Taran, L. S., Elfimova, V. Y., & Streltsov, S. V. (2023). Magnetic Anisotropy of Single-Ion Magnet (PPh4)2 [ReF6]·2H2O. JETP Letters, 117(8), 606-611. https://doi.org/10.1134/S0021364023600623 0021-3640 Final All Open Access, Hybrid Gold https://www.scopus.com/inward/record.uri?eid=2-s2.0-85152675002&doi=10.1134%2fS0021364023600623&partnerID=40&md5=c35de707c72142d4c85d0cd61d8bd633 https://link.springer.com/content/pdf/10.1134/S0021364023600623.pdf http://elar.urfu.ru/handle/10995/130394 10.1134/S0021364023600623 85152675002 000966673800005 |
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| Язык |
en
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| Права |
Open access (info:eu-repo/semantics/openAccess)
cc-by https://creativecommons.org/licenses/by/4.0/ |
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| Формат |
application/pdf
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| Издатель |
Pleiades Publishing
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| Источник |
JETP Letters
JETP Letters |
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