TM-Free and TM-Catalyzed Mechanosynthesis of Functional Polymers
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригинала| Поле | Значение | |
| Заглавие |
TM-Free and TM-Catalyzed Mechanosynthesis of Functional Polymers
|
|
| Автор |
Al-Ithawi, W. K. A.
Khasanov, A. F. Kovalev, I. S. Nikonov, I. L. Platonov, V. A. Kopchuk, D. S. Santra, S. Zyryanov, G. V. Ranu, B. C. |
|
| Тематика |
BALL-MILLING
FUNCTIONAL POLYMERS GREEN CHEMISTRY SOLID-STATE CHEMISTRY SOLVENT-FREE SYNTHESIS TM-CATALYZED SYNTHESIS TM-FREE SYNTHESIS AGRICULTURAL WASTES BALL MILLING CATALYSIS FUNCTIONAL POLYMERS MOLECULES POLYMERIZATION SOLVENTS TRANSITION METALS CATALYZED SYNTHESIS GREEN-CHEMISTRY MECHANOSYNTHESIS METAL TRANSITION METAL-CATALYZED METAL-FREE SYNTHESIS SOLID STATE CHEMISTRY SOLVENT FREE SYNTHESIS TRANSITION-METAL-CATALYZED SYNTHESIS TRANSITION-METAL-FREE SYNTHESIS SUSTAINABLE CHEMISTRY |
|
| Описание |
Highlights: The most representative examples for the TM-free and TM-catalyzed mechano-synthesis of functional polymers are reported; The most common applications for the various types of functional polymers are precented; The advantage of solvent-free mechanosynthesis over conventional solvent-based synthesis are highlighted; In many cases the better performance of the mechanchemically-prepared polymers over those obtained by using conventional methods are demonstrated. Mechanochemically induced methods are commonly used for the depolymerization of polymers, including plastic and agricultural wastes. So far, these methods have rarely been used for polymer synthesis. Compared to conventional polymerization in solutions, mechanochemical polymerization offers numerous advantages such as less or no solvent consumption, the accessibility of novel structures, the inclusion of co-polymers and post-modified polymers, and, most importantly, the avoidance of problems posed by low monomer/oligomer solubility and fast precipitation during polymerization. Consequently, the development of new functional polymers and materials, including those based on mechanochemically synthesized polymers, has drawn much interest, particularly from the perspective of green chemistry. In this review, we tried to highlight the most representative examples of transition-metal (TM)-free and TM-catalyzed mechanosynthesis of some functional polymers, such as semiconductive polymers, porous polymeric materials, sensory materials, materials for photovoltaics, etc. © 2023 by the authors.
Ministry of Education and Science of the Russian Federation, Minobrnauka: 075-15-2022-1118; Council on grants of the President of the Russian Federation: NSh-1223.2022.1.3 This research was funded by the Council for Grants of the President of the Russian Federation, Grant # NSh-1223.2022.1.3 (for the Section 2.3), Ministry of Science and Higher Education of the Russian Federation, Reference # 075-15-2022-1118, dated 29 June 2022 (all other sections). |
|
| Дата |
2024-04-05T16:20:32Z
2024-04-05T16:20:32Z 2023 |
|
| Тип |
Review
Review (info:eu-repo/semantics/review) |info:eu-repo/semantics/publishedVersion |
|
| Идентификатор |
Al-Ithawi, W, Khasanov, A, Kovalev, I, Nikonov, I, Platonov, V, Kopchuk, D, Santra, S, Zyryanov, G & Ranu, B 2023, 'TM-Free and TM-Catalyzed Mechanosynthesis of Functional Polymers', Polymers, Том. 15, № 8, 1853. https://doi.org/10.3390/polym15081853
Al-Ithawi, W., Khasanov, A., Kovalev, I., Nikonov, I., Platonov, V., Kopchuk, D., Santra, S., Zyryanov, G., & Ranu, B. (2023). TM-Free and TM-Catalyzed Mechanosynthesis of Functional Polymers. Polymers, 15(8), [1853]. https://doi.org/10.3390/polym15081853 2073-4360 Final All Open Access, Gold, Green https://www.scopus.com/inward/record.uri?eid=2-s2.0-85154050862&doi=10.3390%2fpolym15081853&partnerID=40&md5=8487c501030e3a3c6a72ea09740a67ea https://www.mdpi.com/2073-4360/15/8/1853/pdf?version=1681297310 http://elar.urfu.ru/handle/10995/130434 10.3390/polym15081853 85154050862 000979078500001 |
|
| Язык |
en
|
|
| Права |
Open access (info:eu-repo/semantics/openAccess)
cc-by https://creativecommons.org/licenses/by/4.0/ |
|
| Формат |
application/pdf
|
|
| Издатель |
MDPI
|
|
| Источник |
Polymers
Polymers |
|