Isobaric Thermal Expansivity and Isothermal Compressibility of Liquid Metals
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригинала| Поле | Значение | |
| Заглавие |
Isobaric Thermal Expansivity and Isothermal Compressibility of Liquid Metals
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| Автор |
Starodubtsev, Y. N.
Tsepelev, V. S. |
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| Тематика |
GRÜNEISEN PARAMETER
INTERNAL PRESSURE ISOBARIC THERMAL EXPANSIVITY ISOTHERMAL COMPRESSIBILITY LIQUID METALS MELTING POINT THERMAL PRESSURE ALKALI METALS ISOTHERMS LIQUID METALS MELTING POINT RARE EARTHS TRANSITION METALS ATOMIC SIZES ATOMIC VIBRATION COHESIVE ENERGIES GRUNEISEN PARAMETERS INTERNAL PRESSURES ISOBARIC THERMAL EXPANSIVITIES ISOTHERMAL COMPRESSIBILITY THERMAL EXPANSIVITY THERMAL PRESSURE THERMODYNAMIC COEFFICIENTS ATOMS |
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| Описание |
The relationship between the volumetric thermodynamic coefficients of liquid metals at the melting point and interatomic bond energy was studied. Using dimensional analysis, we obtained equations that connect cohesive energy with thermodynamic coefficients. The relationships were confirmed by experimental data for alkali, alkaline earth, rare earth, and transition metals. Cohesive energy is proportional to the square root of the ratio of melting point Tm divided by thermal expansivity αp. Thermal expansivity does not depend on the atomic size and atomic vibration amplitude. Bulk compressibility βT and internal pressure pi are related to the atomic vibration amplitude by an exponential dependence. Thermal pressure pth decreases with an increasing atomic size. Fcc and hcp metals with high packing density, as well as alkali metals, have the relationships with the highest coefficient of determination. The contribution of electrons and atomic vibrations to the Grüneisen parameter can be calculated for liquid metals at their melting point. © 2023 by the authors.
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| Дата |
2024-04-05T16:24:35Z
2024-04-05T16:24:35Z 2023 |
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| Тип |
Article
Journal article (info:eu-repo/semantics/article) |info:eu-repo/semantics/publishedVersion |
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| Идентификатор |
Starodubtsev, YN & Tsepelev, VS 2023, 'Isobaric Thermal Expansivity and Isothermal Compressibility of Liquid Metals', Materials, Том. 16, № 10, 3801. https://doi.org/10.3390/ma16103801
Starodubtsev, Y. N., & Tsepelev, V. S. (2023). Isobaric Thermal Expansivity and Isothermal Compressibility of Liquid Metals. Materials, 16(10), [3801]. https://doi.org/10.3390/ma16103801 1996-1944 Final All Open Access, Gold, Green https://www.scopus.com/inward/record.uri?eid=2-s2.0-85160447816&doi=10.3390%2fma16103801&partnerID=40&md5=75ba933906f5f7ee8c8a1a188182d485 https://www.mdpi.com/1996-1944/16/10/3801/pdf?version=1684391830 http://elar.urfu.ru/handle/10995/130525 10.3390/ma16103801 85160447816 000997276700001 |
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| Язык |
en
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| Права |
Open access (info:eu-repo/semantics/openAccess)
cc-by https://creativecommons.org/licenses/by/4.0/ |
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| Формат |
application/pdf
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| Издатель |
MDPI
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| Источник |
Materials
Materials |
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