Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригинала| Поле | Значение | |
| Заглавие |
Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior
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| Автор |
Smirnova, K. A.
Edilova, Y. O. Kiskin, M. A. Bogomyakov, A. S. Kudyakova, Y. S. Valova, M. S. Romanenko, G. V. Slepukhin, P. A. Saloutin, V. I. Bazhin, D. N. |
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| Тематика |
CRYSTAL PACKING
LANTHANIDE LUMINESCENCE SINGLE-ION MAGNET Β-DIKETONATES KETONE DERIVATIVE LANTHANIDE LITHIUM FLUOROCARBON LITHIUM ARTICLE CONTROLLED STUDY CRYSTAL GEOMETRY LUMINESCENCE PHOSPHORESCENCE QUANTUM CHEMISTRY CHEMISTRY LUMINESCENCE FLUOROCARBONS LANTHANOID SERIES ELEMENTS LITHIUM LUMINESCENCE MAGNETS |
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| Описание |
Functionalized perfluoroalkyl lithium β-diketonates (LiL) react with lanthanide(III) salts (Ln = Eu, Gd, Tb, Dy) in methanol to give heterobimetallic Ln-Li complexes of general formula [(LnL3)(LiL)(MeOH)]. The length of fluoroalkyl substituent in ligand was found to affect the crystal packing of complexes. Photoluminescent and magnetic properties of heterobimetallic β-diketonates in the solid state are reported. The effect of the geometry of the [LnO8] coordination environment of heterometallic β-diketonates on the luminescent properties (quantum yields, phosphorescence lifetimes for Eu, Tb, Dy complexes) and single-ion magnet behavior (Ueff for Dy complexes) is revealed. © 2023 by the authors.
Russian Academy of Sciences, РАН: AAAA-A19-119011790132-7 This work carried out in the framework of the basic theme of the Russian Academy of Sciences (state registration № AAAA-A19-119011790132-7). |
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| Дата |
2024-04-05T16:25:50Z
2024-04-05T16:25:50Z 2023 |
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| Тип |
Article
Journal article (info:eu-repo/semantics/article) |info:eu-repo/semantics/publishedVersion |
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| Идентификатор |
Smirnova, KA, Edilova , YO, Kiskin, MA, Bogomyakov, AS, Kudyakova, YS, Valova , MS, Romanenko, GV, Slepukhin, PA, Saloutin, VI & Bazhin, DN 2023, 'Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior', International Journal of Molecular Sciences, Том. 24, № 11, 9778. https://doi.org/10.3390/ijms24119778
Smirnova, K. A., Edilova , Y. O., Kiskin, M. A., Bogomyakov, A. S., Kudyakova, Y. S., Valova , M. S., Romanenko, G. V., Slepukhin, P. A., Saloutin, V. I., & Bazhin, D. N. (2023). Perfluoroalkyl Chain Length Effect on Crystal Packing and [LnO8] Coordination Geometry in Lanthanide-Lithium β-Diketonates: Luminescence and Single-Ion Magnet Behavior. International Journal of Molecular Sciences, 24(11), [9778]. https://doi.org/10.3390/ijms24119778 1661-6596 Final All Open Access, Gold, Green https://www.scopus.com/inward/record.uri?eid=2-s2.0-85161879357&doi=10.3390%2fijms24119778&partnerID=40&md5=23c41e58dd96a458f090a3fb54416f71 https://www.mdpi.com/1422-0067/24/11/9778/pdf?version=1686045544 http://elar.urfu.ru/handle/10995/130558 10.3390/ijms24119778 85161879357 001006406500001 |
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| Язык |
en
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| Права |
Open access (info:eu-repo/semantics/openAccess)
cc-by https://creativecommons.org/licenses/by/4.0/ |
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| Формат |
application/pdf
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| Издатель |
Multidisciplinary Digital Publishing Institute (MDPI)
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| Источник |
International Journal of Molecular Sciences
International Journal of Molecular Sciences |
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