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Polyaromatic Hydrocarbon (PAH)-Based Aza-POPOPs: Synthesis, Photophysical Studies, and Nitroanalyte Sensing Abilities

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Заглавие Polyaromatic Hydrocarbon (PAH)-Based Aza-POPOPs: Synthesis, Photophysical Studies, and Nitroanalyte Sensing Abilities
 
Автор Mohammed, M. S.
Kovalev, I. S.
Slovesnova, N. V.
Sadieva, L. K.
Platonov, V. A.
Novikov, A. S.
Santra, S.
Morozova, J. E.
Zyryanov, G. V.
Charushin, V. N.
Ranu, B. C.
 
Тематика 1,4-BIS(5-PHENYL-2-OXAZOLYL)BENZENE ANALOGUES
AZA-POPOPS
CHEMOSENSORS
CLICK REACTIONS
FLUORESCENCE QUENCHING
NITRO-EXPLOSIVES
PHOTOPHYSICAL STUDIES
1,4 BIS(5 PHENYL 2 OXAZOLYL)BENZENE
COPPER
POLYCYCLIC AROMATIC HYDROCARBON
UNCLASSIFIED DRUG
UNCLASSIFIED DRUG
HYDROCARBON
ARTICLE
CATALYSIS
DRUG SYNTHESIS
FLUORESCENCE
NONHUMAN
FLUORESCENCE
FLUORESCENCE
HYDROCARBONS
 
Описание 1,4-Bis(5-phenyl-2-oxazolyl)benzene (POPOP) is a common scintillation fluorescent laser dye. In this manuscript, the synthesis of 2-Ar-5-(4-(4-Ar’-1H-1,2,3-triazol-1-yl)phenyl)-1,3,4-oxadiazoles (Ar, Ar’ = Ph, naphtalenyl-2, pyrenyl-1, triphenilenyl-2), as PAH-based aza-analogues of POPOP, by means of Cu-catalyzed click reaction between 2-(4-azidophenyl)-5-Ar-1,3,4-oxadiazole and terminal ethynyl-substituted PAHs is reported. An investigation of the photophysical properties of the obtained products was carried out, and their sensory response to nitroanalytes was evaluated. In the case of pyrenyl-1-substituted aza-POPOP, dramatic fluorescence quenching by nitroanalytes was observed. © 2023 by the authors.
Ministry of Education and Science of the Russian Federation, Minobrnauka: 075-15-2022-1118; RUDN University
This research was funded by the Ministry of Science and Higher Education of the Russian Federation (Agreement # 075-15-2022-1118, accessed on 29 June 2022).
The quantum chemical calculations (for A.S.N.) were supported by the RUDN University Strategic Academic Leadership Program.
 
Дата 2024-04-05T16:27:21Z
2024-04-05T16:27:21Z
2023
 
Тип Article
Journal article (info:eu-repo/semantics/article)
|info:eu-repo/semantics/publishedVersion
 
Идентификатор Mohammed, MS, Kovalev, IS, Slovesnova, NV, Sadieva, LK, Platonov, VA, Novikov, AS, Santra, S, Morozova, JE, Zyryanov, GV, Charushin, VN & Ranu, BC 2023, 'Polyaromatic Hydrocarbon (PAH)-Based Aza-POPOPs: Synthesis, Photophysical Studies, and Nitroanalyte Sensing Abilities', International Journal of Molecular Sciences, Том. 24, № 12, 10084. https://doi.org/10.3390/ijms241210084
Mohammed, M. S., Kovalev, I. S., Slovesnova, N. V., Sadieva, L. K., Platonov, V. A., Novikov, A. S., Santra, S., Morozova, J. E., Zyryanov, G. V., Charushin, V. N., & Ranu, B. C. (2023). Polyaromatic Hydrocarbon (PAH)-Based Aza-POPOPs: Synthesis, Photophysical Studies, and Nitroanalyte Sensing Abilities. International Journal of Molecular Sciences, 24(12), [10084]. https://doi.org/10.3390/ijms241210084
1661-6596
Final
All Open Access, Gold, Green
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85163993703&doi=10.3390%2fijms241210084&partnerID=40&md5=0ba15467320a85f13bc4f51ab71310bb
https://www.mdpi.com/1422-0067/24/12/10084/pdf?version=1686659193
http://elar.urfu.ru/handle/10995/130612
10.3390/ijms241210084
85163993703
001014969400001
 
Язык en
 
Права Open access (info:eu-repo/semantics/openAccess)
cc-by
https://creativecommons.org/licenses/by/4.0/
 
Формат application/pdf
 
Издатель Multidisciplinary Digital Publishing Institute (MDPI)
 
Источник International Journal of Molecular Sciences
International Journal of Molecular Sciences