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Assessing geochemical and natural radioactivity impacts of Hamadat phosphatic mine through radiological indices

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Заглавие Assessing geochemical and natural radioactivity impacts of Hamadat phosphatic mine through radiological indices
 
Автор Fathy, D.
Zakaly, H. M. H.
Lasheen, E. S. R.
Elsaman, R.
Alarifi, S. S.
Sami, M.
Awad, H. A.
Ene, A.
 
Тематика APATITE
PHOSPHATE
POTASSIUM 40
RADIUM 226
THORIUM 232
URANIUM
FERRIC ION
PHOSPHORITE
POTASSIUM
RADIUM
RADIUM-226
THORIUM
THORIUM-232
ARTICLE
EGYPT
GAMMA SPECTROMETRY
GEOCHEMICAL ANALYSIS
MINING
NATURAL RADIOACTIVITY
RADIATION HAZARD
PROCEDURES
RADIOACTIVITY
FERRIC COMPOUNDS
POTASSIUM RADIOISOTOPES
RADIATION MONITORING
RADIOACTIVITY
RADIUM
THORIUM
 
Описание The utilization of phosphorite deposits as an industrial resource is of paramount importance, and its sustainability largely depends on ensuring safe and responsible practices. This study aims to evaluate the suitability of phosphorite deposits for industrial applications such as the production of phosphoric acid and phosphatic fertilizers. To achieve this goal, the study meticulously examines the geochemical characteristics of the deposits, investigates the distribution of natural Radioactivity within them, and assesses the potential radiological risk associated with their use. The phosphorites are massive and collected from different beds within the Duwi Formation at the Hamadat mining area. They are grain-supported and composed of phosphatic pellets, bioclasts (bones), non-phosphatic minerals, and cement. Geochemically, phosphorites contain high concentrations of P2O5 (23.59-28.36 wt.%) and CaO (40.85-44.35 wt.%), with low amounts of Al2O3 (0.23-0.51 wt.%), TiO2 (0.01-0.03 wt.%), Fe2O3 (1.14-2.28 wt.%), Na2O (0.37-1.19 wt.%), K2O (0.03-0.12 wt.%), and MnO (0.08- 0.18 wt.%), suggesting the low contribution of the detrital material during their deposition. Moreover, they belong to contain enhanced U concentration (55-128 ppm). They are also enriched with Sr, Ba, Cr, V, and Zn and depleted in Th, Zr, and Rb, which strongly supports the low detrital input during the formation of the Hamadat phosphorites. The high Radioactivity of the studied phosphorites is probably due to the widespread occurrence of phosphatic components (e.g., apatite) that accommodate U in high concentrations. Gamma spectrometry based on NaI (Tl) crystal 3×3 has been used to measure occurring radionuclides in the phosphorite samples. The results indicate that the radioactive concentrations' average values of 226Ra, 232Th, and 40K are 184.18±9.19, 125.82±6.29, and 63.82±3.19 Bq Kg-1 , respectively. Additionally, evaluations have been made of the radiological hazards. The calculated risk indicators exceeded the recommended national and world averages. The data obtained will serve as a reference for follow-up studies to evaluate the effectiveness of the Radioactivity of phosphatic materials collected from the Hamdat mine area. © 2023 Fathy et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
 
Дата 2024-04-05T16:30:30Z
2024-04-05T16:30:30Z
2023
 
Тип Article
Journal article (info:eu-repo/semantics/article)
|info:eu-repo/semantics/publishedVersion
 
Идентификатор Fathy, D, Zakaly, HMH, Lasheen, ESR, Elsaman, R, Alarifi, SS, Sami, M, Awad, HA & Ene, A 2023, 'Assessing geochemical and natural radioactivity impacts of Hamadat phosphatic mine through radiological indices', PLoS ONE, Том. 18, № 8, e0287422. https://doi.org/10.1371/journal.pone.0287422
Fathy, D., Zakaly, H. M. H., Lasheen, E. S. R., Elsaman, R., Alarifi, S. S., Sami, M., Awad, H. A., & Ene, A. (2023). Assessing geochemical and natural radioactivity impacts of Hamadat phosphatic mine through radiological indices. PLoS ONE, 18(8), [e0287422]. https://doi.org/10.1371/journal.pone.0287422
1932-6203
Final
All Open Access, Gold, Green
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85166518303&doi=10.1371%2fjournal.pone.0287422&partnerID=40&md5=574226b00568f98f15a27c7074d025a6
https://journals.plos.org/plosone/article/file?id=10.1371/journal.pone.0287422&type=printable
http://elar.urfu.ru/handle/10995/130689
10.1371/journal.pone.0287422
85166518303
001043333000054
 
Язык en
 
Права Open access (info:eu-repo/semantics/openAccess)
cc-by
https://creativecommons.org/licenses/by/4.0/
 
Формат application/pdf
 
Издатель Public Library of Science
 
Источник PLOS ONE
PLoS ONE