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(E)-2-(6-(4′-(Diphenylamino)-[1,1′-biphenyl]-2-yl)-[1,2,5]oxadiazolo[3,4-b]pyrazin-5(4H)-ylidene)-2-(6-(4′-(diphenylamino)-[1,1′-biphenyl]-2-yl)-[1,2,5]oxadiazolo[3,4-b]pyrazin-5-yl)acetonitrile

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Поле Значение
 
Заглавие (E)-2-(6-(4′-(Diphenylamino)-[1,1′-biphenyl]-2-yl)-[1,2,5]oxadiazolo[3,4-b]pyrazin-5(4H)-ylidene)-2-(6-(4′-(diphenylamino)-[1,1′-biphenyl]-2-yl)-[1,2,5]oxadiazolo[3,4-b]pyrazin-5-yl)acetonitrile
 
Автор Kvashnin, Y. A.
Slepukhin, P. A.
Gazizov, D. A.
Zhilina, E. F.
Rusinov, G. L.
Verbitskiy, E. V.
Charushin, V. N.
 
Тематика 1,2,5-OXADIAZOLO[3,4-B]PYRAZINES
2-CYANOACETIC ACID
ORGANIC SEMICONDUCTORS
 
Описание [1,2,5]Oxadiazolo[3,4-b]pyrazines are of great interest due to their promising photophysical and electrochemical properties, as well their potential use in a wide range of electronic devices. Herein, we report on the preparation of the unexpected product derived from the interaction of 2′-([1,2,5]oxadiazolo[3,4-b]pyrazin-5-yl)-N,N-diphenyl-[1,1′-biphenyl]-4-amine with 2-cyanoacetic acid under basic conditions. The resulting product was characterized using 1H and 13C NMR spectra, high resolution mass spectrometry, Fourier-transform infrared spectroscopy (FTIR), and X-ray diffraction analyses. Furthermore, its photophysical and electrochemical properties were studied using cyclic voltammetry, UV–Vis, and emission spectroscopy. The experimental results have been further rationalized through theoretical DFT calculations. © 2023 by the authors.
Russian Science Foundation, RSF: 19-13-00234
This research was funded by the Russian Science Foundation, grant number No. 19-13-00234.
 
Дата 2024-04-05T16:33:46Z
2024-04-05T16:33:46Z
2023
 
Тип Article
Journal article (info:eu-repo/semantics/article)
|info:eu-repo/semantics/publishedVersion
 
Идентификатор Kvashnin, Y, Slepukhin, P, Gazizov, D, Zhilina, E, Rusinov, G, Verbitskiy, E & Charushin, V 2023, '(E)-2-(6-(4′-(Diphenylamino)-[1,1′-biphenyl]-2-yl)-[1,2,5]oxadiazolo[3,4-b]pyrazin-5(4H)-ylidene)-2-(6-(4′-(diphenylamino)-[1,1′-biphenyl]-2-yl)-[1,2,5]oxadiazolo[3,4-b]pyrazin-5-yl)acetonitrile', Molbank, Том. 2023, № 3, M1714. https://doi.org/10.3390/M1714
Kvashnin, Y., Slepukhin, P., Gazizov, D., Zhilina, E., Rusinov, G., Verbitskiy, E., & Charushin, V. (2023). (E)-2-(6-(4′-(Diphenylamino)-[1,1′-biphenyl]-2-yl)-[1,2,5]oxadiazolo[3,4-b]pyrazin-5(4H)-ylidene)-2-(6-(4′-(diphenylamino)-[1,1′-biphenyl]-2-yl)-[1,2,5]oxadiazolo[3,4-b]pyrazin-5-yl)acetonitrile. Molbank, 2023(3), [M1714]. https://doi.org/10.3390/M1714
1422-8599
Final
All Open Access, Gold
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85172779991&doi=10.3390%2fM1714&partnerID=40&md5=83d6f88b6bcf1ed38b4fee072639bd9e
https://www.mdpi.com/1422-8599/2023/3/M1714/pdf?version=1692582017
http://elar.urfu.ru/handle/10995/130827
10.3390/M1714
85172779991
001074237900001
 
Язык en
 
Связанные ресурсы info:eu-repo/grantAgreement/RSF//19-13-00234
 
Права Open access (info:eu-repo/semantics/openAccess)
cc-by
https://creativecommons.org/licenses/by/4.0/
 
Формат application/pdf
 
Издатель Multidisciplinary Digital Publishing Institute (MDPI)
 
Источник Molbank
MolBank