Fabrication of ternary metal oxide (ZnO:NiO:CuO) nanocomposite heterojunctions for enhanced photocatalytic and antibacterial applications
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригинала| Поле | Значение | |
| Заглавие |
Fabrication of ternary metal oxide (ZnO:NiO:CuO) nanocomposite heterojunctions for enhanced photocatalytic and antibacterial applications
|
|
| Автор |
Ishaque, M. Z.
Zaman, Y. Arif, A. Siddique, A. B. Shahzad, M. Ali, D. Aslam, M. Zaman, H. Faizan, M. |
|
| Тематика |
AROMATIC COMPOUNDS
AZO DYES CITRUS FRUITS COPPER OXIDES DEGRADATION DIELECTRIC LOSSES FOURIER TRANSFORM INFRARED SPECTROSCOPY HETEROJUNCTIONS II-VI SEMICONDUCTORS MOLAR RATIO PHOTOCATALYTIC ACTIVITY WATER POLLUTION ZINC OXIDE ANTIBACTERIALS HYDROTHERMAL METHODS METAL-OXIDE METHYL ORANGE METHYLENE BLUE MOLAR RATIO MONOCLINIC STRUCTURES PHOTO-CATALYTIC SYNTHESISED WILLIAMSON-HALL NANOCOMPOSITES |
|
| Описание |
In this article, ZnO:NiO:CuO nanocomposites (NCPs) were synthesized using a hydrothermal method, with different Zn : Ni : Cu molar ratios (1 : 1 : 1, 2 : 1 : 1, 1 : 2 : 1, and 1 : 1 : 1). The PXRD confirmed the formation of a NCP consisting of ZnO (hexagonal), NiO (cubic), and CuO (monoclinic) structures. The crystallite sizes of NCPs were calculated using Debye Scherrer and Williamson-Hall methods. The calculated crystalline sizes (Scherrer method) of the NCPs were determined to be 21, 27, 23, and 20 nm for the molar ratios 1 : 1 : 1, 2 : 1 : 1, 1 : 2 : 1, and 1 : 1 : 2, respectively. FTIR spectra confirmed the successful formation of heterojunction NCPs via the presence of metal-oxygen bonds. The UV-vis spectroscopy was used to calculate the bandgap of synthesized samples and was found in the range of 2.99-2.17 eV. SEM images showed the mixed morphology of NCPs i.e., irregular spherical and rod-like structures. The dielectric properties, including AC conductivity, dielectric constant, impedance, and dielectric loss parameters were measured using an LCR meter. The DC electrical measurements revealed that NCPs have a high electrical conductivity. All the NCPs were evaluated for the photocatalytic degradation of Methylene blue (MB), methyl orange (MO), and a mixture of both of these dyes. The NCPs with a molar ratio 1 : 1 : 2 (Zn : Ni : Cu) displayed outstanding photocatalytic activity under sunlight, achieving the degradation efficiency of 98% for methylene blue (MB), 92% for methyl orange (MO) and more than 87% in the case of a mixture of dyes within just 90 minutes of illumination. The antibacterial activity results showed the more noxious nature of NCPs against Gram-negative bacteria with a maximum zone of inhibition revealed by the NCPs of molar ratio 1 : 2 : 1 (Zn : Ni : Cu). On the basis of these observations, it can be anticipated that the NCPs can be successfully employed for the purification of contaminated water by the degradation of hazardous organic compounds and in antibacterial ointments. © 2023 The Royal Society of Chemistry.
King Saud University, KSU The authors extend their appreciation to Researchers Supporting Project number (RSP2023R165), King Saud University, Riyadh, Saudi Arabia. |
|
| Дата |
2024-04-05T16:35:30Z
2024-04-05T16:35:30Z 2023 |
|
| Тип |
Article
Journal article (info:eu-repo/semantics/article) |info:eu-repo/semantics/publishedVersion |
|
| Идентификатор |
Ishaque, MZ, Zaman, Y, Arif, A, Siddique, AB, Shahzad, M, Ali, D, Aslam, M, Zaman, H & Faizan, M 2023, 'Fabrication of ternary metal oxide (ZnO:NiO:CuO) nanocomposite heterojunctions for enhanced photocatalytic and antibacterial applications', RSC Advances, Том. 13, № 44, стр. 30838-30854. https://doi.org/10.1039/D3RA05170F
Ishaque, M. Z., Zaman, Y., Arif, A., Siddique, A. B., Shahzad, M., Ali, D., Aslam, M., Zaman, H., & Faizan, M. (2023). Fabrication of ternary metal oxide (ZnO:NiO:CuO) nanocomposite heterojunctions for enhanced photocatalytic and antibacterial applications. RSC Advances, 13(44), 30838-30854. https://doi.org/10.1039/D3RA05170F 2046-2069 Final All Open Access, Gold, Green https://www.scopus.com/inward/record.uri?eid=2-s2.0-85175842825&doi=10.1039%2fd3ra05170f&partnerID=40&md5=73b3d065e222f849d1c8c284ddb46d4b https://pubs.rsc.org/en/content/articlepdf/2023/ra/d3ra05170f http://elar.urfu.ru/handle/10995/130923 10.1039/d3ra05170f 85175842825 001086988800001 |
|
| Язык |
en
|
|
| Права |
Open access (info:eu-repo/semantics/openAccess)
cc-by-nc https://creativecommons.org/licenses/by-nc/4.0/ |
|
| Формат |
application/pdf
|
|
| Издатель |
Royal Society of Chemistry
|
|
| Источник |
RSC Advances
RSC Advances |
|