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Computer Simulation of Thermal Processes Involving Sr and Ca Radionuclides in the Process of Heating Radioactive Graphite in an Air Atmosphere

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Заглавие Computer Simulation of Thermal Processes Involving Sr and Ca Radionuclides in the Process of Heating Radioactive Graphite in an Air Atmosphere
 
Автор Barbin, N. M.
Titov, S. A.
Terentiev, D. I.
Kobelev, A. M.
 
Тематика AIR ATMOSPHERE
EQUILIBRIUM CONSTANT
HEATING
RADIOACTIVE GRAPHITE
RADIONUCLIDES
THERMAL PROCESSES
THERMODYNAMIC SIMULATION
 
Описание The paper presents the results from a thermodynamic analysis of the behavior of Sr and Ca radionuclides in the process of heating radioactive graphite in an air atmosphere. The TERRA software package was used for the thermodynamic analysis in a temperature range of 300 to 3600 K to determine the possible composition of the ionized, gaseous and condensed phases. It has been found that strontium is in the form of condensed SrCl2(k) and gaseous SrCl2 in a temperature range of 300 to 1600 K, and in the form of gaseous SrCl2, SrO, SrCl and Sr and ionized SrCl+, Sr+ and SrO+ when the temperature is increased from 1600 to 3600 K. Calcium is in the form of condensed CaCl2(k), CaUO4(k), CaO(k) and gaseous CaCl2 in the temperature interval between 300 and 2100 K, and in the form of gaseous Ca, CaCl and CaO and ionized Ca+, CaO+ and CaCl+ when the temperature is increased from 2100 to 3600 K. The paper determines the key reactions within individual phases and among condensed, gaseous and ionized phases. The equilibrium constants of their reactions have been calculated. Based on the results obtained, dependence plots are presented for the Sr and Ca radionuclide distribution by phases. © 2023 Obninsk Institute for Nuclear Power Engineering, National Research Nuclear University 'MEPhI'. All rights reserved.
 
Дата 2024-04-05T16:37:37Z
2024-04-05T16:37:37Z
2023
 
Тип Article
Journal article (info:eu-repo/semantics/article)
|info:eu-repo/semantics/publishedVersion
 
Идентификатор Барбин, НМ, Титов, СА, Терентьев, ДИ & Кобелев, АМ 2023, 'Компьютерное моделирование термических процессов с участием радионуклидов Sr, Ca при нагревании радиоактивного графита в атмосфере воздуха', Известия высших учебных заведений. Ядерная энергетика, № 3, стр. 106-117. https://doi.org/10.26583/npe.2023.3.09
Барбин, Н. М., Титов, С. А., Терентьев, Д. И., & Кобелев, А. М. (2023). Компьютерное моделирование термических процессов с участием радионуклидов Sr, Ca при нагревании радиоактивного графита в атмосфере воздуха. Известия высших учебных заведений. Ядерная энергетика, (3), 106-117. https://doi.org/10.26583/npe.2023.3.09
0204-3327
Final
All Open Access, Bronze
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85179605162&doi=10.26583%2fnpe.2023.3.09&partnerID=40&md5=b3713c167454d61818c824d751367635
https://static.nuclear-power-engineering.ru/articles/2023/03/09.pdf
http://elar.urfu.ru/handle/10995/131048
54696766
10.26583/npe.2023.3.09
85179605162
 
Язык ru
 
Права Open access (info:eu-repo/semantics/openAccess)
 
Формат application/pdf
 
Издатель Obninsk Institute for Nuclear Power Engineering, National Research Nuclear University 'MEPhI'
 
Источник Izvestiya Wysshikh Uchebnykh Zawedeniy, Yadernaya Energetika
Izvestiya Wysshikh Uchebnykh Zawedeniy, Yadernaya Energetika