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Computer simulation of thermal processes involving Sr and Ca radionuclides in the process of heating radioactive graphite in an air atmosphere

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Заглавие Computer simulation of thermal processes involving Sr and Ca radionuclides in the process of heating radioactive graphite in an air atmosphere
 
Автор Barbin, N. M.
Titov, S. A.
Terentiev, D. I.
Kobelev, A. M.
 
Тематика AIR ATMOSPHERE
EQUILIBRIUM CONSTANT
HEATING
RADIOACTIVE GRAPHITE
RADIONUCLIDES
THERMAL PROCESSES
THERMODYNAMIC SIMULATION
 
Описание The paper presents the results from a thermodynamic analysis of the behavior of Sr and Ca radionuclides in the process of heating radioactive graphite in an air atmosphere. The TERRA software package was used for the thermodynamic analysis in a temperature range of 300 to 3600 K to determine the possible composition of the ionized, gaseous and condensed phases. It has been found that strontium is in the form of condensed SrCl2(c) and gaseous SrCl2 in a temperature range of 300 to 1600 K, and in the form of gaseous SrCl2, SrO, SrCl and Sr and ionized SrCl+, Sr+ and SrO+ when the temperature is increased from 1600 to 3600 K. Calcium is in the form of condensed CaCl2(c), CaUO4(c), CaO(c) and gaseous CaCl2 in the temperature interval between 300 and 2100 K, and in the form of gaseous Ca, CaCl and CaO and ionized Ca+, CaO+ and CaCl+ when the temperature is increased from 2100 to 3600 K. The paper determines the key reactions within individual phases and among condensed, gaseous and ionized phases. The equilibrium constants of their reactions have been calculated. Based on the results obtained, dependence plots are presented for the Sr and Ca radionuclide distribution by phases. © Barbin NM et al.
 
Дата 2024-04-05T16:38:55Z
2024-04-05T16:38:55Z
2023
 
Тип Article
Journal article (info:eu-repo/semantics/article)
|info:eu-repo/semantics/publishedVersion
 
Идентификатор Barbin, NM, Titov, SA, Terentiev, DI & Kobelev, AM 2023, 'Computer simulation of thermal processes involving Sr and Ca radionuclides in the process of heating radioactive graphite in an air atmosphere', Nuclear Energy and Technology, Том. 9, № 4, стр. 273-279. https://doi.org/10.3897/nucet.9.116661
Barbin, N. M., Titov, S. A., Terentiev, D. I., & Kobelev, A. M. (2023). Computer simulation of thermal processes involving Sr and Ca radionuclides in the process of heating radioactive graphite in an air atmosphere. Nuclear Energy and Technology, 9(4), 273-279. https://doi.org/10.3897/nucet.9.116661
2452-3038
Final
All Open Access, Gold
https://www.scopus.com/inward/record.uri?eid=2-s2.0-85181908857&doi=10.3897%2fnucet.9.116661&partnerID=40&md5=7b95f48ed1ddb62a1a84c6d47f0fb5e2
https://nucet.pensoft.net/article/116661/download/pdf/
http://elar.urfu.ru/handle/10995/131112
10.3897/nucet.9.116661
85181908857
 
Язык en
 
Права Open access (info:eu-repo/semantics/openAccess)
cc-by
https://creativecommons.org/licenses/by/4.0/
 
Формат application/pdf
 
Издатель Pensoft Publishers
 
Источник Nuclear Energy and Technology
Nuclear Energy and Technology