Frequency comb-referenced cavity ring-down spectroscopy of natural water between 8041 and 8633 cm−1
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригиналаПоле | Значение | |
Заглавие |
Frequency comb-referenced cavity ring-down spectroscopy of natural water between 8041 and 8633 cm−1
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Автор |
Koroleva, A. O.
Mikhailenko, S. N. Kassi, S. Campargue, A. |
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Тематика |
CAVITY RING-DOWN SPECTROSCOPY
FREQUENCY COMB H2O HITRAN ROVIBRATIONAL ASSIGNMENTS WATER ABSORPTION SPECTROSCOPY BAND STRUCTURE INFRARED DEVICES LIGHT MEASUREMENT VARIATIONAL TECHNIQUES WATER ABSORPTION CAVITY RING DOWN SPECTROSCOPIES FREQUENCY COMBS H2O HITRAN LINE INTENSITIES LINE PARAMETERS LINE POSITIONS NATURAL WATERS ROVIBRATIONAL ASSIGNMENT WATER VAPOUR WATER VAPOR COMPARATIVE STUDY DATABASE ISOTOPIC COMPOSITION NEAR INFRARED SPECTROSCOPY WATER VAPOR |
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Описание |
The 1.25 µm atmospheric transparency window is of importance for a number of atmospheric applications. As a continuation of our previous works on the improvement of water vapor line parameters in the near infrared, the room temperature absorption spectrum of water vapor in natural isotopic abundance is recorded with unprecedented sensitivity between 8041 and 8633 cm−1, using comb-referenced cavity ring-down spectroscopy. The line positions and intensities of more than 5400 lines were retrieved. Their intensities range between 3.6 × 10−30 and 1.5 × 10−22 cm/molecule. The high sensitivity and low noise level of the recordings (αmin≈ 10−11 cm−1) allow for measuring more than 1600 new lines and determine their positions with an accuracy of about 10−4 cm−1 in the case of isolated features. The rovibrational assignments were performed using known experimental energy levels and calculated spectra based on variational calculations by Schwenke and Partridge. The final line list is assigned to more than 5400 transitions of the first six water isotopologues (H216O, H218O, H217O, HD16O, HD18O and HD17O). The measured line positions allow to determine the energy of 79 new levels of H216O, H218O, H217O, and HD16O, and to correct 139 previously reported term values. Although a good agreement is generally observed, the comparison to the HITRAN2020 spectroscopic database and to the W2020 transition frequencies reveals a number of discrepancies both for line positions and line intensities. The lack of traceability of some HITRAN line parameters and some biases in the derivation procedure of the W2020 energy levels are confirmed in the studied range. Validation tests of the theoretical values of the line intensities against measured values show both band-by-band variations of the deviations on the order of a few % and line-by-line fluctuations within a given band. © 2023 Elsevier Ltd
Centre National de la Recherche Scientifique, CNRS; Russian Science Foundation, RSF: 18-11-00024-Π The support of CNRS (France) in the frame of the International Research Project SAMIA is acknowledged. SNM activity was supported in the frame of the Russian Science Foundation, grant no. 18-11-00024-Π. The support of CNRS (France) in the frame of the International Research Project SAMIA is acknowledged. SNM activity was supported in the frame of the Russian Science Foundation , grant no. 18-11-00024-Π . |
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Дата |
2024-04-05T16:39:08Z
2024-04-05T16:39:08Z 2023 |
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Тип |
Article
Journal article (info:eu-repo/semantics/article) |info:eu-repo/semantics/acceptedVersion |
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Идентификатор |
Koroleva, AO, Mikhailenko, SN, Kassi, S & Campargue, A 2023, 'Frequency comb-referenced cavity ring-down spectroscopy of natural water between 8041 and 8633 cm−1', Journal of Quantitative Spectroscopy and Radiative Transfer, Том. 298, стр. 108489. https://doi.org/10.1016/j.jqsrt.2023.108489
Koroleva, A. O., Mikhailenko, S. N., Kassi, S., & Campargue, A. (2023). Frequency comb-referenced cavity ring-down spectroscopy of natural water between 8041 and 8633 cm−1. Journal of Quantitative Spectroscopy and Radiative Transfer, 298, 108489. https://doi.org/10.1016/j.jqsrt.2023.108489 0022-4073 Final All Open Access, Green https://www.scopus.com/inward/record.uri?eid=2-s2.0-85147124180&doi=10.1016%2fj.jqsrt.2023.108489&partnerID=40&md5=babd08d540b360fd19f816cd421ba87a http://manuscript.elsevier.com/S0022407323000079/pdf/S0022407323000079.pdf http://elar.urfu.ru/handle/10995/131125 10.1016/j.jqsrt.2023.108489 85147124180 000964971000001 |
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Язык |
en
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Связанные ресурсы |
info:eu-repo/grantAgreement/RSF//18-11-00024
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Права |
Open access (info:eu-repo/semantics/openAccess)
publisher-specific-oa |
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Формат |
application/pdf
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Издатель |
Elsevier Ltd
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Источник |
Journal of Quantitative Spectroscopy and Radiative Transfer
Journal of Quantitative Spectroscopy and Radiative Transfer |
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