Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2 with Competing Nearest-Neighbor and Next-Nearest-Neighbor Intrachain Exchange Interactions
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригиналаПоле | Значение | |
Заглавие |
Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2 with Competing Nearest-Neighbor and Next-Nearest-Neighbor Intrachain Exchange Interactions
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Автор |
Markina, M.
Zakharov, K. Ovchenkov, Y. Pashkov, G. Lyssenko, K. Berdonosov, P. Pchelkina, Z. Vasiliev, A. |
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Тематика |
LINARITE
LOW-DIMENSIONAL MAGNETISM MAGNETIC PHASE DIAGRAM DENSITY FUNCTIONAL THEORY PERMITTIVITY SATURATION MAGNETIZATION SPECIFIC HEAT DIELECTRIC PERMITTIVITIES HYDROTHERMALLY LINARITE LOW-DIMENSIONAL MAGNETISM MAGNETIC PHASE DIAGRAMS MEASUREMENTS OF NEAREST-NEIGHBOUR QUASI-ONE DIMENSIONAL QUASI-ONE-DIMENSIONAL SYNTHESISED SELENIUM COMPOUNDS |
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Описание |
PbCu(SeO4)(OH)2, the selenate sibling of the mineral linarite, was synthesized hydrothermally, investigated in measurements of magnetization M, specific heat Cp and dielectric permittivity ε, and analyzed within density functional theory formalism. This quasi-one-dimensional compound evidences formation of a short-range correlation regime at T* ~ 8 K and experiences a long-range magnetic order at TN = 4.3 K. A magnetization saturation of approximately 1 µB is reached at µ0Hflip ~ 16 T preceded by a jump at µ0Hflop = 2.4 T. Additionally, there are multiple indicators of the formation of an additional electrically active phase above the Neel temperature, which suggests that PbCu(SeO4)(OH)2 is a multiferroic system. © 2022 by the authors.
Russian Foundation for Basic Research, РФФИ, (20-02-00015) Russian Science Foundation, RSF, (22-22-00023) Government Council on Grants, Russian Federation, (075-15-2021-604) X-ray data were collected using the equipment provided by the Moscow State University Development Program. P.S.B. acknowledges support by the Megagrant program of the Government of Russian Federation through the project 075-15-2021-604. A.N.V. and Z.V.P. acknowledge support by the Russian Science Foundation through the project 22-22-00023. M.M.M. acknowledges support by the Russian Foundation for Basic Research through the project 20-02-00015. |
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Дата |
2024-04-08T11:06:05Z
2024-04-08T11:06:05Z 2022 |
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Тип |
Article
Journal article (info:eu-repo/semantics/article) Published version (info:eu-repo/semantics/publishedVersion) |
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Идентификатор |
Markina, M, Zakharov, K, Ovchenkov, Y, Pashkov, G, Lyssenko, K, Berdonosov, P, Pchelkina, Z & Vasiliev, A 2022, 'Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2 with Competing Nearest-Neighbor and Next-Nearest-Neighbor Intrachain Exchange Interactions', Materials, Том. 15, № 21, 7860. https://doi.org/10.3390/ma15217860
Markina, M., Zakharov, K., Ovchenkov, Y., Pashkov, G., Lyssenko, K., Berdonosov, P., Pchelkina, Z., & Vasiliev, A. (2022). Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2 with Competing Nearest-Neighbor and Next-Nearest-Neighbor Intrachain Exchange Interactions. Materials, 15(21), [7860]. https://doi.org/10.3390/ma15217860 1996-1944 Final All Open Access; Gold Open Access; Green Open Access https://www.mdpi.com/1996-1944/15/21/7860/pdf?version=1667895952 https://www.mdpi.com/1996-1944/15/21/7860/pdf?version=1667895952 http://elar.urfu.ru/handle/10995/131275 10.3390/ma15217860 85141852390 000883463700001 |
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Язык |
en
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Связанные ресурсы |
info:eu-repo/grantAgreement/RSF//22-22-00023
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Права |
Open access (info:eu-repo/semantics/openAccess)
cc-by https://creativecommons.org/licenses/by/4.0/ |
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Формат |
application/pdf
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Издатель |
MDPI
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Источник |
Materials
Materials |
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