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Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2 with Competing Nearest-Neighbor and Next-Nearest-Neighbor Intrachain Exchange Interactions

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Заглавие Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2 with Competing Nearest-Neighbor and Next-Nearest-Neighbor Intrachain Exchange Interactions
 
Автор Markina, M.
Zakharov, K.
Ovchenkov, Y.
Pashkov, G.
Lyssenko, K.
Berdonosov, P.
Pchelkina, Z.
Vasiliev, A.
 
Тематика LINARITE
LOW-DIMENSIONAL MAGNETISM
MAGNETIC PHASE DIAGRAM
DENSITY FUNCTIONAL THEORY
PERMITTIVITY
SATURATION MAGNETIZATION
SPECIFIC HEAT
DIELECTRIC PERMITTIVITIES
HYDROTHERMALLY
LINARITE
LOW-DIMENSIONAL MAGNETISM
MAGNETIC PHASE DIAGRAMS
MEASUREMENTS OF
NEAREST-NEIGHBOUR
QUASI-ONE DIMENSIONAL
QUASI-ONE-DIMENSIONAL
SYNTHESISED
SELENIUM COMPOUNDS
 
Описание PbCu(SeO4)(OH)2, the selenate sibling of the mineral linarite, was synthesized hydrothermally, investigated in measurements of magnetization M, specific heat Cp and dielectric permittivity ε, and analyzed within density functional theory formalism. This quasi-one-dimensional compound evidences formation of a short-range correlation regime at T* ~ 8 K and experiences a long-range magnetic order at TN = 4.3 K. A magnetization saturation of approximately 1 µB is reached at µ0Hflip ~ 16 T preceded by a jump at µ0Hflop = 2.4 T. Additionally, there are multiple indicators of the formation of an additional electrically active phase above the Neel temperature, which suggests that PbCu(SeO4)(OH)2 is a multiferroic system. © 2022 by the authors.
Russian Foundation for Basic Research, РФФИ, (20-02-00015)
Russian Science Foundation, RSF, (22-22-00023)
Government Council on Grants, Russian Federation, (075-15-2021-604)
X-ray data were collected using the equipment provided by the Moscow State University Development Program. P.S.B. acknowledges support by the Megagrant program of the Government of Russian Federation through the project 075-15-2021-604. A.N.V. and Z.V.P. acknowledge support by the Russian Science Foundation through the project 22-22-00023. M.M.M. acknowledges support by the Russian Foundation for Basic Research through the project 20-02-00015.
 
Дата 2024-04-08T11:06:05Z
2024-04-08T11:06:05Z
2022
 
Тип Article
Journal article (info:eu-repo/semantics/article)
Published version (info:eu-repo/semantics/publishedVersion)
 
Идентификатор Markina, M, Zakharov, K, Ovchenkov, Y, Pashkov, G, Lyssenko, K, Berdonosov, P, Pchelkina, Z & Vasiliev, A 2022, 'Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2 with Competing Nearest-Neighbor and Next-Nearest-Neighbor Intrachain Exchange Interactions', Materials, Том. 15, № 21, 7860. https://doi.org/10.3390/ma15217860
Markina, M., Zakharov, K., Ovchenkov, Y., Pashkov, G., Lyssenko, K., Berdonosov, P., Pchelkina, Z., & Vasiliev, A. (2022). Quasi-One-Dimensional Linarite-Type PbCu(SeO4)(OH)2 with Competing Nearest-Neighbor and Next-Nearest-Neighbor Intrachain Exchange Interactions. Materials, 15(21), [7860]. https://doi.org/10.3390/ma15217860
1996-1944
Final
All Open Access; Gold Open Access; Green Open Access
https://www.mdpi.com/1996-1944/15/21/7860/pdf?version=1667895952
https://www.mdpi.com/1996-1944/15/21/7860/pdf?version=1667895952
http://elar.urfu.ru/handle/10995/131275
10.3390/ma15217860
85141852390
000883463700001
 
Язык en
 
Связанные ресурсы info:eu-repo/grantAgreement/RSF//22-22-00023
 
Права Open access (info:eu-repo/semantics/openAccess)
cc-by
https://creativecommons.org/licenses/by/4.0/
 
Формат application/pdf
 
Издатель MDPI
 
Источник Materials
Materials