Trapping of Ag+ into a Perfect Six-Coordinated Environment: Structural Analysis, Quantum Chemical Calculations and Electrochemistry
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригинала| Поле | Значение | |
| Заглавие |
Trapping of Ag+ into a Perfect Six-Coordinated Environment: Structural Analysis, Quantum Chemical Calculations and Electrochemistry
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| Автор |
Komlyagina, V. I.
Romashev, N. F. Kokovkin, V. V. Gushchin, A. L. Benassi, E. Sokolov, M. N. Abramov, P. A. |
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| Тематика |
AG
COMPLEXES CRYSTAL STRUCTURE CYCLIC VOLTAMMETRY DFT CALCULATIONS DPP-BIAN POLYOXOMOLYBDATES REDOX-ACTIVE LIGANDS ACENAPHTHENES CARBON DIOXIDE ELECTROCHEMISTRY LIGANDS MODELS, MOLECULAR MOLECULAR STRUCTURE ACENAPHTHENE DERIVATIVE CARBON DIOXIDE LIGAND CHEMICAL STRUCTURE CHEMISTRY ELECTROCHEMISTRY MOLECULAR MODEL |
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| Описание |
Self-assembly of (Bu4N)4[β-Mo8O26], AgNO3, and 2-bis[(2,6-diisopropylphenyl)-imino]acenaphthene (dpp-bian) in DMF solution resulted in the (Bu4N)2[β-{Ag(dpp-bian)}2Mo8O26] (1) complex. The complex was characterized by single crystal X-ray diffraction (SCXRD), X-ray powder diffraction (XRPD), diffuse reflectance (DR), infrared spectroscopy (IR), and elemental analysis. Comprehensive SCXRD studies of the crystal structure show the presence of Ag+ in an uncommon coordination environment without a clear preference for Ag-N over Ag-O bonding. Quantum chemical calculations were performed to qualify the nature of the Ag-N/Ag-O interactions and to assign the electronic transitions observed in the UV–Vis absorption spectra. The electrochemical behavior of the complex combines POM and redox ligand signatures. Complex 1 demonstrates catalytic activity in the electrochemical reduction of CO2. © 2022 by the authors.
Council on grants of the President of the Russian Federation, (MD-396.2021.1.3) This work was supported by the grant of the President of the Russian Federation for young scientists—Doctors of Sciences MD-396.2021.1.3. |
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| Дата |
2024-04-08T11:06:37Z
2024-04-08T11:06:37Z 2022 |
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| Тип |
Article
Journal article (info:eu-repo/semantics/article) Published version (info:eu-repo/semantics/publishedVersion) |
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| Идентификатор |
Komlyagina, VI, Romashev, NF, Kokovkin, VV, Gushchin, AL, Benassi, E, Sokolov, MN & Abramov, PA 2022, 'Trapping of Ag+ into a Perfect Six-Coordinated Environment: Structural Analysis, Quantum Chemical Calculations and Electrochemistry', Molecules, Том. 27, № 20, 6961. https://doi.org/10.3390/molecules27206961
Komlyagina, V. I., Romashev, N. F., Kokovkin, V. V., Gushchin, A. L., Benassi, E., Sokolov, M. N., & Abramov, P. A. (2022). Trapping of Ag+ into a Perfect Six-Coordinated Environment: Structural Analysis, Quantum Chemical Calculations and Electrochemistry. Molecules, 27(20), [6961]. https://doi.org/10.3390/molecules27206961 1420-3049 Final All Open Access; Gold Open Access; Green Open Access https://www.mdpi.com/1420-3049/27/20/6961/pdf?version=1666743224 https://www.mdpi.com/1420-3049/27/20/6961/pdf?version=1666743224 http://elar.urfu.ru/handle/10995/131321 10.3390/molecules27206961 85140872997 000872803200001 |
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| Язык |
en
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| Права |
Open access (info:eu-repo/semantics/openAccess)
cc-by https://creativecommons.org/licenses/by/4.0/ |
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| Формат |
application/pdf
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| Издатель |
MDPI
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| Источник |
Molecules
Molecules |
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