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Synthesis and Photophysical Properties of α-(N-Biphenyl)-Substituted 2,2′-Bipyridine-Based Push–Pull Fluorophores

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Заглавие Synthesis and Photophysical Properties of α-(N-Biphenyl)-Substituted 2,2′-Bipyridine-Based Push–Pull Fluorophores
 
Автор Starnovskaya, E. S.
Kopchuk, D. S.
Khasanov, A. F.
Taniya, O. S.
Nikonov, I. L.
Valieva, M. I.
Pavlyuk, D. E.
Novikov, A. S.
Zyryanov, G. V.
Chupakhin, O. N.
 
Тематика AIEE
FLUORESCENCE
FLUOROSOLVATOCHROMIC PROPERTIES
HAMMETT CONSTANTS
LIPPERT–MATAGA EQUATION
NITROEXPLOSIVE DETECTION
Α-(N-BIPHENYL)-SUBSTITUTED 2,2′-BIPYRIDINES
“PUSH–PULL” FLUOROPHORES
2,2'-DIPYRIDYL
BIPHENYL COMPOUNDS
FLUORESCENT DYES
IONOPHORES
TRIAZINES
2,2' BIPYRIDINE
BIPHENYL
BIPHENYL DERIVATIVE
FLUORESCENT DYE
IONOPHORE
TRIAZINE DERIVATIVE
 
Описание A series of new α-(N-biphenyl)-substituted 2,2′-bipyridines were obtained through the combination of the ipso-nucleophilic aromatic substitution of the C5-cyano group, aza-Diels–Alder and Suzuki cross-coupling reactions, starting from 5-cyano-1,2,4-triazines. For the obtained compounds, photophysical and fluorosolvatochromic properties were studied. Fluorophores 3l and 3b demonstrated unexpected AIEE activity, while 3a and 3h showed promising nitroexplosive detection abilities. © 2022 by the authors.
Russian Science Foundation, RSF, (21-13-00304)
Council on grants of the President of the Russian Federation, (075-15-2022-802, NSh- 1223.2022.1.3)
RUDN University
This research was funded by the Russian Scientific Foundation, grant number 19-73-10144-P dated 2 August 2022 (Photophysical Studies and Studies of Fluorosolvatochromism) and 21-13-00304 dated 19 April 2021 (AIEE Studies)), by the Grants Council of the President of the Russian Federation (grant number NSh- 1223.2022.1.3, state contract № 075-15-2022-802 dated 6 May 2022) and the RUDN University Strategic Academic Leadership Program.
 
Дата 2024-04-08T11:06:37Z
2024-04-08T11:06:37Z
2022
 
Тип Article
Journal article (info:eu-repo/semantics/article)
Published version (info:eu-repo/semantics/publishedVersion)
 
Идентификатор Starnovskaya, ES, Kopchuk, DS, Khasanov, AF, Taniya, OS, Nikonov, IL, Valieva, MI, Pavlyuk, DE, Novikov, AS, Zyryanov, GV & Chupakhin, ON 2022, 'Synthesis and Photophysical Properties of α-(N-Biphenyl)-Substituted 2,2′-Bipyridine-Based Push–Pull Fluorophores', Molecules, Том. 27, № 20, 6879. https://doi.org/10.3390/molecules27206879
Starnovskaya, E. S., Kopchuk, D. S., Khasanov, A. F., Taniya, O. S., Nikonov, I. L., Valieva, M. I., Pavlyuk, D. E., Novikov, A. S., Zyryanov, G. V., & Chupakhin, O. N. (2022). Synthesis and Photophysical Properties of α-(N-Biphenyl)-Substituted 2,2′-Bipyridine-Based Push–Pull Fluorophores. Molecules, 27(20), [6879]. https://doi.org/10.3390/molecules27206879
1420-3049
Final
All Open Access; Gold Open Access; Green Open Access
https://www.mdpi.com/1420-3049/27/20/6879/pdf?version=1666684460
https://www.mdpi.com/1420-3049/27/20/6879/pdf?version=1666684460
http://elar.urfu.ru/handle/10995/131322
10.3390/molecules27206879
85140873129
000872811600001
 
Язык en
 
Связанные ресурсы info:eu-repo/grantAgreement/RSF//21-13-00304
 
Права Open access (info:eu-repo/semantics/openAccess)
cc-by
https://creativecommons.org/licenses/by/4.0/
 
Формат application/pdf
 
Издатель MDPI
 
Источник Molecules
Molecules