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Carbon Paper Modified with Functionalized Poly(diallyldimethylammonium chloride) Graphene and Gold Phytonanoparticles as a Promising Sensing Material: Characterization and Electroanalysis of Ponceau 4R in Food Samples

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Заглавие Carbon Paper Modified with Functionalized Poly(diallyldimethylammonium chloride) Graphene and Gold Phytonanoparticles as a Promising Sensing Material: Characterization and Electroanalysis of Ponceau 4R in Food Samples
 
Автор Stozhko, N. Y.
Khamzina, E. I.
Bukharinova, M. A.
Tarasov, A. V.
Kolotygina, V. Y.
Lakiza, N. V.
Kuznetcova, E. D.
 
Тематика CANDIES
CARBON PAPER/VEIL
ELECTROCHEMICAL SENSOR
ELECTROSENSING
FOOD DYE
FUNCTIONALIZED GRAPHENE
GOLD PHYTONANOPARTICLES
NANOMODIFIER
POLY(DIALLYLDIMETHYLAMMONIUM CHLORIDE)
PONCEAU 4R
POPSICLES
SENSING MATERIAL
SOFT DRINKS
«GREEN» SYNTHESIS
 
Описание This paper presents a novel eco-friendly sensing material based on carbon paper (CP) volumetrically modified with a composite nanomodifier that includes functionalized poly(diallyldimethylammonium chloride) graphene (PDDA-G) and phytosynthesized gold nanoparticles (phyto-AuNPs). The functionalization of graphene was justified by Fourier-transform infrared spectroscopy. The phyto-AuNPs (d = 6 nm) were prepared by “green” synthesis with the use of strawberry leaf extract. The sensing material was characterized using scanning electron microscopy, electrochemical impedance spectroscopy, and voltammetry. The research results indicated a more than double increase in the electroactive surface area; a decrease in the resistance of electron transfer on nanocomposite-modified CP, compared to bare CP. The phyto-AuNPs/PDDA-G/CP was used for the electrosensing of the synthetic dye Ponceau 4R. The oxidation signal of colorant enhanced 4-fold on phyto-AuNPs/PDDA-G/CP in comparison to CP. The effect of the quantity of nanomodifier, solution pH, potential scan rate, accumulation parameters, and differential pulse parameters on the peak current of Ponceau 4R was studied. Under optimal conditions, excellent sensory characteristics were established: LOD 0.6 nM and LR 0.001–2 μM for Ponceau 4R. High selectivity and sensitivity enable the use of the sensor for analyzing the content of Ponceau 4R in food products (soft drinks, candies, and popsicles) without additional sample preparation. © 2022 by the authors.
 
Дата 2024-04-08T11:06:51Z
2024-04-08T11:06:51Z
2022
 
Тип Article
Journal article (info:eu-repo/semantics/article)
Published version (info:eu-repo/semantics/publishedVersion)
 
Идентификатор Stozhko, NY, Khamzina, EI, Bukharinova, MA, Tarasov, AV, Kolotygina, VY, Lakiza, NV & Kuznetcova, ED 2022, 'Carbon Paper Modified with Functionalized Poly(diallyldimethylammonium chloride) Graphene and Gold Phytonanoparticles as a Promising Sensing Material: Characterization and Electroanalysis of Ponceau 4R in Food Samples', Nanomaterials, Том. 12, № 23, 4197. https://doi.org/10.3390/nano12234197
Stozhko, N. Y., Khamzina, E. I., Bukharinova, M. A., Tarasov, A. V., Kolotygina, V. Y., Lakiza, N. V., & Kuznetcova, E. D. (2022). Carbon Paper Modified with Functionalized Poly(diallyldimethylammonium chloride) Graphene and Gold Phytonanoparticles as a Promising Sensing Material: Characterization and Electroanalysis of Ponceau 4R in Food Samples. Nanomaterials, 12(23), [4197]. https://doi.org/10.3390/nano12234197
2079-4991
Final
All Open Access; Gold Open Access; Green Open Access
https://www.mdpi.com/2079-4991/12/23/4197/pdf?version=1669616448
https://www.mdpi.com/2079-4991/12/23/4197/pdf?version=1669616448
http://elar.urfu.ru/handle/10995/131356
10.3390/nano12234197
85143714267
000897979800001
 
Язык en
 
Права Open access (info:eu-repo/semantics/openAccess)
cc-by
https://creativecommons.org/licenses/by/4.0/
 
Формат application/pdf
 
Издатель MDPI
 
Источник Nanomaterials
Nanomaterials