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Brief Review on High-Temperature Electrochemical Hydrogen Sensors

Электронный научный архив УРФУ

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Поле Значение
 
Заглавие Brief Review on High-Temperature Electrochemical Hydrogen Sensors
 
Автор Gorbova, E.
Balkourani, G.
Molochas, C.
Sidiropoulos, D.
Brouzgou, A.
Demin, A.
Tsiakaras, P.
 
Тематика AMPEROMETRIC SENSOR
DIFFUSION BARRIER
ELECTROCHEMICAL CELL
HYDROGEN AND STEAM DETECTION
LIMITING CURRENT
SOLID OXIDE ELECTROLYTES
 
Описание Hydrogen sensors, especially those operating at high temperatures, are essential tools for the emerging hydrogen economy. Monitoring hydrogen under process conditions to control the reactions for detecting confined species is crucial to the safe, widespread use and public acceptance of hydrogen as fuel. Hydrogen sensors must have a sensitivity ranging from traces of hydrogen (parts per million (ppm)) up to levels near the lower explosive limit (LEL = 4% H2 in the air) for safety reasons. Furthermore, they need to operate in cryogenic, ambient, and high-temperature environments. Herein, emphasis is given to hydrogen sensors based on solid oxide electrolytes (operating at high temperatures), in particular oxygen ion and proton conductors. The review is devoted to potentiometric, amperometric, and combined amperometric-potentiometric hydrogen sensors. Experimental results already reported in the international literature are presented and analyzed to reveal the configuration, principle of operation, and the applied solid electrolytes and electrodes of the high-temperature hydrogen sensors. Additionally, an amperometric sensor able to detect hydrogen and steam in atmospheric air through a two-stage procedure is presented and thoroughly discussed. The discussion reveals that high-temperature hydrogen sensors face different challenges in terms of the electrodes and solid electrolytes to be used, depending on the operating principle of each sensor type. © 2022 by the authors.
Hellenic Foundation for Research and Innovation, ΕΛ.ΙΔ.Ε.Κ, (5426, 5869)
Georgia Balkourani thankfully acknowledges the Hellenic Foundation for Research and Innovation (H.F.R.I.) for the funding under the “3rd Call for H.F.R.I. Ph.D. Fellowships” (Fellowship Number: 5869). The research of Costas Molochas was supported by the Hellenic Foundation for Research and Innovation (HFRI) under the 3rd Call for HFRI PhD Fellowships (Fellowship Number: 5426).
 
Дата 2024-04-08T11:08:00Z
2024-04-08T11:08:00Z
2022
 
Тип Review
Review (info:eu-repo/semantics/review)
Published version (info:eu-repo/semantics/publishedVersion)
 
Идентификатор Gorbova, E, Balkourani, G, Molochas, C, Sidiropoulos, D, Brouzgou, A, Demin, A & Tsiakaras, P 2022, 'Brief Review on High-Temperature Electrochemical Hydrogen Sensors', Catalysts, Том. 12, № 12, 1647. https://doi.org/10.3390/catal12121647
Gorbova, E., Balkourani, G., Molochas, C., Sidiropoulos, D., Brouzgou, A., Demin, A., & Tsiakaras, P. (2022). Brief Review on High-Temperature Electrochemical Hydrogen Sensors. Catalysts, 12(12), [1647]. https://doi.org/10.3390/catal12121647
2073-4344
Final
All Open Access; Gold Open Access
https://www.mdpi.com/2073-4344/12/12/1647/pdf?version=1671089537
https://www.mdpi.com/2073-4344/12/12/1647/pdf?version=1671089537
http://elar.urfu.ru/handle/10995/131555
10.3390/catal12121647
85144898393
000902363200001
 
Язык en
 
Права Open access (info:eu-repo/semantics/openAccess)
cc-by
https://creativecommons.org/licenses/by/4.0/
 
Формат application/pdf
 
Издатель MDPI
 
Источник Catalysts
Catalysts