Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригинала| Поле | Значение | |
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Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins
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| Автор |
Grzhegorzhevskii, K.
Haouas, M. Lion, M. Vashurin, A. Denikaev, A. Marfin, Y. Kim, G. Falaise, C. Cadot, E. |
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| Тематика |
MAGNETIC RESONANCE SPECTROSCOPY
NANOSPHERES PORPHYRINS MORPHOLOGY OLIGOMERS X RAY SCATTERING CATION NANOSPHERE OLIGOMER POLYANION POLYOXOMETALATE PORPHYRIN UNCLASSIFIED DRUG CATIONIC PORPHYRIN HIERARCHICAL ORGANIZATIONS HYBRID OLIGOMERS INORGANIC NANOSPHERES IONIC INTERACTION MULTISCALE METHOD NONCOVALENT PHOTOPHYSICAL SMALL ANGLE X-RAY SCATTERING SUPRAMOLECULAR ASSEMBLIES AQUEOUS SOLUTION ARTICLE CHEMICAL STRUCTURE CONTROLLED STUDY DIFFUSION COEFFICIENT MOLECULAR INTERACTION MORPHOLOGY PROTON NUCLEAR MAGNETIC RESONANCE STOICHIOMETRY SURFACE PROPERTY TITRIMETRY X RAY CRYSTALLOGRAPHY CHEMISTRY NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY PORPHYRINS |
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| Описание |
Noncovalent ionic interactions between nanosized Keplerate-type capsules {Mo132} and tetra-cationic porphyrins have been investigated in aqueous solution using small-angle X-ray scattering, 1H NMR and photophysical methods. These complementary multiscale methods reveal the formation of large hybrid oligomers built from a short-range organization in which the cationic porphyrin is glued onto the large POM surface. The local structuring appears to be strongly dependent on the dye : {Mo132} ratio changing the morphology of the oligomers from linear to dense aggregates. © 2023 The Royal Society of Chemistry.
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| Дата |
2024-04-22T15:52:57Z
2024-04-22T15:52:57Z 2022 |
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| Тип |
Article
Journal article (info:eu-repo/semantics/article) info:eu-repo/semantics/submittedVersion |
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| Идентификатор |
Grzhegorzhevskii, K, Haouas, M, Lion, M, Vashurin, A, Denikaev, A, Marfin, Y, Kim, G, Falaise, C & Cadot, E 2022, 'Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins', Chemical Communications, Том. 59, № 1, стр. 86-89. https://doi.org/10.1039/D2CC05193A
Grzhegorzhevskii, K., Haouas, M., Lion, M., Vashurin, A., Denikaev, A., Marfin, Y., Kim, G., Falaise, C., & Cadot, E. (2022). Gigantic supramolecular assemblies built from dynamic hierarchical organization between inorganic nanospheres and porphyrins. Chemical Communications, 59(1), 86-89. https://doi.org/10.1039/D2CC05193A 1359-7345 Final All Open Access; Green Open Access https://hal.science/hal-03936892/file/Manuscript_Grzhegorzhevskii%20KV_21092022_Revised.pdf https://hal.science/hal-03936892/file/Manuscript_Grzhegorzhevskii%20KV_21092022_Revised.pdf http://elar.urfu.ru/handle/10995/132372 10.1039/d2cc05193a 85143967787 902043400001 |
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| Язык |
en
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| Права |
Open access (info:eu-repo/semantics/openAccess)
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| Формат |
application/pdf
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| Издатель |
Royal Society of Chemistry
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| Источник |
Chemical Communications
Chemical Communications |
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