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The appearance of Ti3+ states in solution-processed TiOx buffer layers in inverted organic photovoltaics

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Заглавие The appearance of Ti3+ states in solution-processed TiOx buffer layers in inverted organic photovoltaics
 
Автор Zhidkov, I. S.
McLeod, J. A.
Kurmaev, E. Z.
Korotin, M. A.
Kukharenko, A. I.
Savva, A.
Choulis, S. A.
Korotin, D. M.
Cholakh, S. O.
 
Тематика CORE LEVELS
ELECTRONIC STRUCTURE
ENERGY GAP
TEMPERATURE
DEFECT STATE
ELECTRONIC STRUCTURE CALCULATIONS
LOW TEMPERATURE SOLUTIONS
ORGANIC PHOTOVOLTAIC (OPV)
ORGANIC PHOTOVOLTAICS
SELECTIVE CONTACTS
SOLUTION-PROCESSED
X RAY PHOTOELECTRON SPECTROSCOPY
 
Описание We study the low-temperature solution processed TiOx films and device structures using core level and valence X-ray photoelectron spectroscopy (XPS) and electronic structure calculations. We are able to correlate the fraction of Ti3+ present as obtained from Ti 2p core level XPS with the intensity of the defect states that appear within the band gap as observed with our valence XPS. Constructing an operating inverted organic photovoltaic (OPV) using the TiOx film as an electron selective contact may increase the fraction of Ti3+ present. We provide evidence that the number of charge carriers in TiOx can be significantly varied and this might influence the performance of inverted OPVs. © 2016 Author(s).
National Natural Science Foundation of China, NSFC: 11404232; Research Promotion Foundation, RPF: NEA TPATH/0308/06; China Postdoctoral Science Foundation: 2014M551645; Russian Science Foundation, RSF: 14-22-00004; European Regional Development Fund, FEDER; Government Council on Grants, Russian Federation
This research was done with partial support from the Government of the Russian Federation (Act 211, Agreement No. 02.A03.21.0006), the European Regional Development Fund, and the Republic of Cyprus through the Research Promotion Foundation (Strategic Infrastructure Project NEA TPATH/0308/06), the National Natural Science Foundation of China (Project No. 11404232), and the China Postdoctoral Science Foundation (Project No. 2014M551645). The CPA calculations were supported by the Russian Science Foundation (Project No. 14-22-00004).
 
Дата 2024-04-22T18:30:06Z
2024-04-22T18:30:06Z
2016
 
Тип Article
Journal article (info:eu-repo/semantics/article)
info:eu-repo/semantics/submittedVersion
 
Идентификатор Zhidkov, IS, McLeod, JA, Kurmaev, EZ, Korotin, MA, Kukharenko, AI, Savva, A, Choulis, SA, Korotin, DM & Cholakh, SO 2016, 'The appearance of Ti3+ states in solution-processed TiOx buffer layers in inverted organic photovoltaics', Applied Physics Letters, vol. 109, no. 2, 022108. https://doi.org/10.1063/1.4958892
Zhidkov, I. S., McLeod, J. A., Kurmaev, E. Z., Korotin, M. A., Kukharenko, A. I., Savva, A., Choulis, S. A., Korotin, D. M., & Cholakh, S. O. (2016). The appearance of Ti3+ states in solution-processed TiOx buffer layers in inverted organic photovoltaics. Applied Physics Letters, 109(2), [022108]. https://doi.org/10.1063/1.4958892
0003-6951
Final
All Open Access, Green
https://ktisis.cut.ac.cy/bitstream/20.500.14279/9120/2/coulis%2c%20savva.pdf
http://elar.urfu.ru/handle/10995/132511
10.1063/1.4958892
84978732072
000381155200034
 
Язык en
 
Права Open access (info:eu-repo/semantics/openAccess)
 
Формат application/pdf
 
Издатель American Institute of Physics Inc.
 
Источник Applied Physics Letters
Applied Physics Letters