Chirality-Dependent Growth of Self-Assembled Diphenylalanine Microtubes
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригинала| Поле | Значение | |
| Заглавие |
Chirality-Dependent Growth of Self-Assembled Diphenylalanine Microtubes
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| Автор |
Zelenovskiy, P. S.
Nuraeva, A. S. Kopyl, S. Arkhipov, S. G. Vasilev, S. G. Bystrov, V. S. Gruzdev, D. A. Waliczek, M. Svitlyk, V. Shur, V. Y. Mafra, L. Kholkin, A. L. Шур, В. Я. |
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| Тематика |
CHIRALITY
CRYSTAL STRUCTURE ENANTIOMERS DI-PEPTIDES EXPERIMENTAL CONDITIONS MICRO-TUBES MOLECULAR MECHANICS METHOD SPACE GROUPS STRUCTURAL UNIT GROWTH KINETICS |
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| Описание |
The difference in the crystal structure and growth kinetics of microtubes formed from l- and d-enantiomers of diphenylalanine dipeptide is investigated both experimentally and theoretically by computer simulation. The microtubes of l- and d-enantiomers grown simultaneously and under identical experimental conditions possess different crystallographic space groups, have essential difference in sizes, and demonstrate different growth kinetics. Computer simulation by molecular mechanics methods revealed a fundamental difference in the interaction between structural units of microtubes of different chiralities. A model describing chirality-dependent growth of microtubes is proposed. © 2019 American Chemical Society.
Russian Foundation for Basic Research, RFBR: 19-01-00519A, TUBITAK/0006/2014, UID/CTM/50011/2019; Russian Science Foundation, RSF: 18-72-00052 The measurements of microtubes growth kinetics and morphology analysis were done in Ural Federal University (UrFU). This part of the research was made possible by Russian Science Foundation (Grant No. 18-72-00052). The equipment of the Ural Center for Shared Use “Modern nanotechnology” UrFU was used. Computer simulation was performed under the support of Russian Foundation for Basic Research (Grant No. 19-01-00519A). X-ray diffraction data were collected under the experiment SC-4587 at the European Synchrotron Radiation Source (ESRF, Grenoble, France). S.K., P.Z., L.M., and A.K. are grateful to FCT project PTDC/CTM-CTM/31679/2017 (CENTRO-01-0145-FEDER-031679). P.Z. and L.M. are grateful to FCT project PTDC/QEQ-QAN/6373/2014. S.K and A.K were also supported by the joint Portugal-Turkey project (TUBITAK/0006/2014). Part of this work was developed within the scope of the project CICECO-Aveiro Institute of Materials, FCT ref. UID/CTM/50011/2019, financed by national funds through the FCT/MCTES in the scope of the framework contract foreseen in the numbers 4, 5 and 6 of the article 23, of the Decree-Law 57/2016, of August 29, changed by Law 57/2017, of July 19. |
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| Дата |
2024-04-23T11:10:52Z
2024-04-23T11:10:52Z 2019 |
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| Тип |
Article
Journal article (info:eu-repo/semantics/article) info:eu-repo/semantics/acceptedVersion |
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| Идентификатор |
Zelenovskiy, P. S., Nuraeva, A. S., Kopyl, S., Arkhipov, S. G., Vasilev, S. G., Bystrov, V. S., … Kholkin, A. L. (2019). Chirality-dependent growth of self-assembled diphenylalanine microtubes. Crystal Growth & Design, 19(11), 6414–6421. doi:10.1021/acs.cgd.9b00884
1528-7483 Final All Open Access, Green https://researchrepository.ul.ie/articles/journal_contribution/Chirality-dependent_growth_of_self-assembled_diphenylalanine_microtubes/19816579/1/files/35223781.pdf http://elar.urfu.ru/handle/10995/132547 10.1021/acs.cgd.9b00884 85067931289 000495768200050 |
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| Язык |
en
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| Права |
Open access (info:eu-repo/semantics/openAccess)
cc-by-nc-sa |
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| Формат |
application/pdf
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| Издатель |
American Chemical Society
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| Источник |
Crystal Growth & Design
Crystal Growth and Design |
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