Construction and solution of a Wannier-functions based Hamiltonian in the pseudopotential plane-wave framework for strongly correlated materials
Электронный научный архив УРФУ
Информация об архиве | Просмотр оригиналаПоле | Значение | |
Заглавие |
Construction and solution of a Wannier-functions based Hamiltonian in the pseudopotential plane-wave framework for strongly correlated materials
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Автор |
Korotin, Dm.
Kozhevnikov, A. V. Skornyakov, S. L. Leonov, I. Binggeli, N. Anisimov, V. I. Trimarchi, G. |
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Тематика |
AB INITIO APPROACH
AB-INITIO BASIS SETS CALCULATION SCHEME CHALLENGING PROBLEM CHARGE-TRANSFER INSULATORS CORRELATED MATERIALS CORRELATION EFFECTS DENSITY FUNCTIONAL THEORY CALCULATIONS DYNAMICAL MEAN-FIELD THEORY HAMILTONIAN HAMILTONIAN PARAMETERS INTERACTION PARAMETERS NARROW BANDS PHOTOEMISSION SPECTRUM PLANE WAVES PSEUDO POTENTIALS PSEUDO-POTENTIAL PLANE WAVE METHODS QUANTUM MONTE CARLO METHODS WANNIER WANNIER FUNCTIONS CHARGE TRANSFER CRYSTAL IMPURITIES EMISSION SPECTROSCOPY HAMILTONIANS ION EXCHANGE MEAN FIELD THEORY NICKEL NICKEL OXIDE PROBABILITY DENSITY FUNCTION DENSITY FUNCTIONAL THEORY |
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Описание |
Ab initio determination of model Hamiltonian parameters for strongly correlated materials is a key issue in applying many-particle theoretical tools to real narrow-band materials. We propose a selfcontained calculation scheme to construct, with an ab initio approach, and solve such a Hamiltonian. The scheme uses a Wannier-function-basis set, with the Coulomb interaction parameter U obtained specifically for theseWannier functions via constrained Density functional theory (DFT) calculations. The Hamiltonian is solved by Dynamical Mean-Field Theory (DMFT) with the effective impurity problem treated by the Quantum Monte Carlo (QMC) method. Our scheme is based on the pseudopotential plane-wave method, which makes it suitable for developments addressing the challenging problem of crystal structural relaxations and transformations due to correlation effects. We have applied our scheme to the "charge transfer insulator" material nickel oxide and demonstrate a good agreement with the experimental photoemission spectra. © 2008 Springer.
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Дата |
2024-04-24T12:38:26Z
2024-04-24T12:38:26Z 2008 |
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Тип |
Article
Journal article (info:eu-repo/semantics/article) info:eu-repo/semantics/submittedVersion |
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Идентификатор |
Korotin, D., Kozhevnikov, A. V., Skornyakov, S. L., Leonov, I., Binggeli, N., Anisimov, V. I., & Trimarchi, G. (2008). Construction and solution of a Wannier-functions based Hamiltonian in the pseudopotential plane-wave framework for strongly correlated materials. The European Physical Journal. B, 65(1), 91–98. doi:10.1140/epjb/e2008-00326-3
1434-6028 Final All Open Access, Green https://arxiv.org/pdf/0801.3500 http://elar.urfu.ru/handle/10995/132603 10.1140/epjb/e2008-00326-3 |
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Язык |
en
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Права |
Open access (info:eu-repo/semantics/openAccess)
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Формат |
application/pdf
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Издатель |
Springer Science and Business Media LLC
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Источник |
The European Physical Journal B
European Physical Journal B |
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